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Reid, Michael S.
Publications (7 of 7) Show all publications
Vanderfleet, O., Reid, M. S., Bras, J., Heux, L., Godoy, J., Panga, M. & Cranston, E. (2019). Effects of degree of polymerization, surface chemistry, and surface charge density on cellulose nanocrystal thermal stability. Paper presented at National Meeting of the American-Chemical-Society (ACS), MAR 31-APR 04, 2019, Orlando, FL. Abstracts of Papers of the American Chemical Society, 257
Open this publication in new window or tab >>Effects of degree of polymerization, surface chemistry, and surface charge density on cellulose nanocrystal thermal stability
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2019 (English)In: Abstracts of Papers of the American Chemical Society, ISSN 0065-7727, Vol. 257Article in journal, Meeting abstract (Other academic) Published
Place, publisher, year, edition, pages
AMER CHEMICAL SOC, 2019
National Category
Paper, Pulp and Fiber Technology
Identifiers
urn:nbn:se:kth:diva-257619 (URN)000478860502755 ()
Conference
National Meeting of the American-Chemical-Society (ACS), MAR 31-APR 04, 2019, Orlando, FL
Note

QC 20190918

Available from: 2019-09-18 Created: 2019-09-18 Last updated: 2019-09-18Bibliographically approved
Reid, M. S., Erlandsson, J. & Wågberg, L. (2019). Incorporation of cellulose nanocrystals into polyamide nanocomposites with controlled architecture via interfacial polymerization. Paper presented at National Meeting of the American-Chemical-Society (ACS), MAR 31-APR 04, 2019, Orlando, FL. Abstracts of Papers of the American Chemical Society, 257
Open this publication in new window or tab >>Incorporation of cellulose nanocrystals into polyamide nanocomposites with controlled architecture via interfacial polymerization
2019 (English)In: Abstracts of Papers of the American Chemical Society, ISSN 0065-7727, Vol. 257Article in journal, Meeting abstract (Other academic) Published
Place, publisher, year, edition, pages
AMER CHEMICAL SOC, 2019
National Category
Paper, Pulp and Fiber Technology
Identifiers
urn:nbn:se:kth:diva-257610 (URN)000478860502418 ()
Conference
National Meeting of the American-Chemical-Society (ACS), MAR 31-APR 04, 2019, Orlando, FL
Note

QC 20190918

Available from: 2019-09-18 Created: 2019-09-18 Last updated: 2019-09-18Bibliographically approved
Vanderfleet, O. M., Reid, M. S., Bras, J., Heux, L., Godoy-Vargas, J., Panga, M. K. & Cranston, E. D. (2019). Insight into thermal stability of cellulose nanocrystals from new hydrolysis methods with acid blends. Cellulose (London), 26(1), 507-528
Open this publication in new window or tab >>Insight into thermal stability of cellulose nanocrystals from new hydrolysis methods with acid blends
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2019 (English)In: Cellulose (London), ISSN 0969-0239, E-ISSN 1572-882X, Vol. 26, no 1, p. 507-528Article in journal (Refereed) Published
Abstract [en]

Abstract: This study provides insight into the thermal degradation of cotton cellulose nanocrystals (CNCs) by tuning their physico-chemical properties through acid hydrolysis using blends of phosphoric and sulfuric acid. CNCs isolated by sulfuric acid hydrolysis are known to degrade at lower temperatures than CNCs hydrolyzed with phosphoric acid; however, the reason for this change is unclear. Although all CNCs are inherently relatively thermally stable, their application in polymer composites and liquid formulations designed to function at high temperatures could be extended if thermal stability was improved. Herein, thermogravimetric analysis was carried out on six types of CNCs (in both acid and sodium form) with different surface chemistry, surface charge density, dimensions, crystallinity and degree of polymerization (DP) to identify the key properties that influence thermal stability of nanocellulose. In acid form, CNC surface charge density was found to be the determining factor in thermal stability due to de-esterification and acid-catalyzed degradation. Conversely, in sodium form, surface chemistry and charge density had a negligible effect on the onset of thermal degradation, however, the DP of the cellulose polymer chains highly influenced stability. The presence of more reducing ends in lower DP nanocrystals is inferred to facilitate thermally-induced depolymerization and degradation. Degree of crystallinity did not significantly affect CNC thermal stability. Studying CNCs produced from single or blends of acids (and changing the counterion) elucidated the thermal behavior of cellulose and furthermore demonstrated new routes to tailor CNCs thermal and colloidal stability. Graphical abstract: [Figure not available: see fulltext.].

Place, publisher, year, edition, pages
Springer Netherlands, 2019
Keywords
Acid hydrolysis, Cellulose nanocrystals, Degree of polymerization, Nanocellulose, Phosphoric acid, Thermal stability, Cellulose, Charge density, Chemical analysis, Degradation, Hydrolysis, Nanocrystals, Polymerization, Sodium, Stability, Sulfuric acid, Surface chemistry, Thermodynamic stability, Thermogravimetric analysis, Acid-catalyzed degradation, Cellulose nano-crystals, Degree of crystallinity, Liquid formulations, Physicochemical property, Sulfuric acid hydrolysis, Cellulose derivatives, Gravimetry, Thermal Analysis
National Category
Chemical Engineering
Identifiers
urn:nbn:se:kth:diva-248282 (URN)10.1007/s10570-018-2175-7 (DOI)000458742600027 ()2-s2.0-85058103428 (Scopus ID)
Note

QC 20190405

Available from: 2019-04-05 Created: 2019-04-05 Last updated: 2019-04-05Bibliographically approved
Reid, M. S., Erlandsson, J. & Wågberg, L. (2019). Interfacial Polymerization of Cellulose Nanocrystal Polyamide Janus Nanocomposites with Controlled Architectures. ACS Macro Letters, 8(10), 1334-1340
Open this publication in new window or tab >>Interfacial Polymerization of Cellulose Nanocrystal Polyamide Janus Nanocomposites with Controlled Architectures
2019 (English)In: ACS Macro Letters, E-ISSN 2161-1653, Vol. 8, no 10, p. 1334-1340Article in journal (Refereed) Published
Abstract [en]

The widespread use of renewable nanomaterials has been limited due to poor integration with conventional polymer matrices. Often, chemical and physical surface modifications are implemented to improve compatibility, however, this comes with environmental and economic cost. This work demonstrates that renewable nanomaterials, specifically cellulose nanocrystals (CNCs), can be utilized in their unmodified state and presents a simple and versatile, one-step method to produce polyamide/CNC nanocomposites with unique Janus-like properties. Nanocomposites in the form of films, fibers, and capsules are prepared by dispersing as-prepared CNCs in the aqueous phase prior to the interfacial polymerization of aromatic diamines and acyl chlorides. The diamines in the aqueous phase not only serve as a monomer for polymerization, but additionally, adsorb to and promote the incorporation of CNCs into the nanocomposite. Regardless of the architecture, CNCs are only present along the surface facing the aqueous phase, resulting in materials with unique, Janus-like wetting behavior and potential applications in filtration, separations, drug delivery, and advanced fibers.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2019
National Category
Polymer Chemistry
Identifiers
urn:nbn:se:kth:diva-263348 (URN)10.1021/acsmacrolett.9b00692 (DOI)000491220800022 ()2-s2.0-85073169510 (Scopus ID)
Note

QC 20191119

Available from: 2019-11-19 Created: 2019-11-19 Last updated: 2019-11-25Bibliographically approved
Tian, W., VahidMohammadi, A., Reid, M. S., Wang, Z., Ouyang, L., Erlandsson, J., . . . Hamedi, M. (2019). Multifunctional Nanocomposites with High Strength and Capacitance Using 2D MXene and 1D Nanocellulose. Advanced Materials, Article ID 1902977.
Open this publication in new window or tab >>Multifunctional Nanocomposites with High Strength and Capacitance Using 2D MXene and 1D Nanocellulose
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2019 (English)In: Advanced Materials, ISSN 0935-9648, E-ISSN 1521-4095, article id 1902977Article in journal (Refereed) Published
Abstract [en]

The family of two-dimensional (2D) metal carbides and nitrides, known as MXenes, are among the most promising electrode materials for supercapacitors thanks to their high metal-like electrical conductivity and surface-functional-group-enabled pseudocapacitance. A major drawback of these materials is, however, the low mechanical strength, which prevents their applications in lightweight, flexible electronics. A strategy of assembling freestanding and mechanically robust MXene (Ti3C2Tx) nanocomposites with one-dimensional (1D) cellulose nanofibrils (CNFs) from their stable colloidal dispersions is reported. The high aspect ratio of CNF (width of approximate to 3.5 nm and length reaching tens of micrometers) and their special interactions with MXene enable nanocomposites with high mechanical strength without sacrificing electrochemical performance. CNF loading up to 20%, for example, shows a remarkably high mechanical strength of 341 MPa (an order of magnitude higher than pristine MXene films of 29 MPa) while still maintaining a high capacitance of 298 F g(-1) and a high conductivity of 295 S cm(-1). It is also demonstrated that MXene/CNF hybrid dispersions can be used as inks to print flexible micro-supercapacitors with precise dimensions. This work paves the way for fabrication of robust multifunctional MXene nanocomposites for printed and lightweight structural devices.

Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH, 2019
Keywords
2D titanium carbide, MXenes, nanocellulose, nanocomposites, supercapacitors
National Category
Polymer Chemistry
Identifiers
urn:nbn:se:kth:diva-257809 (URN)10.1002/adma.201902977 (DOI)000482085200001 ()31408235 (PubMedID)2-s2.0-85070724702 (Scopus ID)
Note

QC 20190912

Available from: 2019-09-12 Created: 2019-09-12 Last updated: 2019-09-12Bibliographically approved
Yang, X., Reid, M. S., Olsén, P. & Berglund, L.Eco-Friendly Cellulose Nanofibrils Designed by Nature: Effects from Preserving Native State.
Open this publication in new window or tab >>Eco-Friendly Cellulose Nanofibrils Designed by Nature: Effects from Preserving Native State
(English)Manuscript (preprint) (Other academic)
National Category
Materials Engineering Paper, Pulp and Fiber Technology
Identifiers
urn:nbn:se:kth:diva-262841 (URN)
Note

QC 20191023

Available from: 2019-10-21 Created: 2019-10-21 Last updated: 2019-10-23Bibliographically approved
Träger, A., Reid, M. S., Pendergraph, S. A., Cobo Sanchez, C., Malmström, E. & Wågberg, L.Enhanced toolbox to tailor theproperties of Layer‐by‐Layer assembled triblock copolymer films.
Open this publication in new window or tab >>Enhanced toolbox to tailor theproperties of Layer‐by‐Layer assembled triblock copolymer films
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(English)Manuscript (preprint) (Other academic)
National Category
Polymer Chemistry
Identifiers
urn:nbn:se:kth:diva-263103 (URN)
Note

QC 20191104

Available from: 2019-10-29 Created: 2019-10-29 Last updated: 2019-11-04Bibliographically approved
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