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2024 (engelsk)Inngår i: International journal of hydrogen energy, ISSN 0360-3199, E-ISSN 1879-3487, Vol. 49, s. 459-471Artikkel i tidsskrift (Annet vitenskapelig) Published
Abstract [en]
The global Sustainable Development Goals highlight the necessity for affordable and clean energy, designated as SDG7. A sustainable and feasible biorefinery concept is proposed for the carbon-negative utilization of biomass waste for affordable H2 and battery anode material production. Specifically, an innovative tandem biocarbon + NiAlO + biocarbon catalyst strategy is constructed to realize a complete reforming of biomass pyro-vapors into H2+CO (as a mixture). The solid residues from pyrolysis are upgraded into high-quality hard carbon (HCs), demonstrating potential as sodium ion battery (SIBs) anodes. The product, HC-1600-6h, exhibited great electrochemical performance when employed as (SIBs) anodes (full cell: 263 Wh/kg with ICE of 89%). Ultimately, a comprehensive process is designed, simulated, and evaluated. The process yields 75 kg H2, 169 kg HCs, and 891 kg captured CO2 per ton of biomass achieving approx. 100% carbon and hydrogen utilization efficiencies. A life cycle assessment estimates a biomass valorization process with negative-emissions (−0.81 kg CO2/kg-biomass, reliant on Sweden wind electricity). A techno-economic assessment forecasts a notably profitable process capable of co-producing affordable H2 and hard carbon battery anodes. The payback period of the process is projected to fall within two years, assuming reference prices of 13.7 €/kg for HCs and 5 €/kg for H2. The process contributes to a novel business paradigm for sustainable and commercially viable biorefinery process, achieving carbon-negative valorization of biomass waste into affordable energy and materials.
sted, utgiver, år, opplag, sider
Elsevier BV, 2024
Emneord
Biomass, Pyrolysis, Catalytic reforming, Biochar, Syngas, Auger
HSV kategori
Forskningsprogram
Energiteknik; Kemiteknik; Teknisk materialvetenskap
Identifikatorer
urn:nbn:se:kth:diva-339172 (URN)10.1016/j.ijhydene.2023.09.096 (DOI)001132794800001 ()2-s2.0-85172247785 (Scopus ID)
Forskningsfinansiär
Vinnova, 2021-03735
Merknad
QC 20231106
2023-11-032023-11-032025-02-25bibliografisk kontrollert