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2023 (English)In: Nature Communications, E-ISSN 2041-1723, Vol. 14, no 1, article id 3305Article in journal (Refereed) Published
Abstract [en]
Silica glass is a high-performance material used in many applications such as lenses, glassware, and fibers. However, modern additive manufacturing of micro-scale silica glass structures requires sintering of 3D-printed silica-nanoparticle-loaded composites at similar to 1200 degrees C, which causes substantial structural shrinkage and limits the choice of substrate materials. Here, 3D printing of solid silica glass with sub-micrometer resolution is demonstrated without the need of a sintering step. This is achieved by locally crosslinking hydrogen silsesquioxane to silica glass using nonlinear absorption of sub-picosecond laser pulses. The as-printed glass is optically transparent but shows a high ratio of 4-membered silicon-oxygen rings and photoluminescence. Optional annealing at 900 degrees C makes the glass indistinguishable from fused silica. The utility of the approach is demonstrated by 3D printing an optical microtoroid resonator, a luminescence source, and a suspended plate on an optical-fiber tip. This approach enables promising applications in fields such as photonics, medicine, and quantum-optics.
Place, publisher, year, edition, pages
Springer Nature, 2023
National Category
Materials Engineering
Identifiers
urn:nbn:se:kth:diva-330534 (URN)10.1038/s41467-023-38996-3 (DOI)001002780300001 ()37280208 (PubMedID)2-s2.0-85161049960 (Scopus ID)
Note
QC 20230630
2023-06-302023-06-302023-11-25Bibliographically approved