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Odnevall Wallinder, IngerORCID iD iconorcid.org/0000-0003-2206-0082
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Publications (10 of 178) Show all publications
Zhang, X., Odnevall Wallinder, I. & Leygraf, C. (2018). Atmospheric corrosion of Zn-Al coatings in a simulated automotive environment. Surface Engineering, 34(9), 641-648
Open this publication in new window or tab >>Atmospheric corrosion of Zn-Al coatings in a simulated automotive environment
2018 (English)In: Surface Engineering, ISSN 0267-0844, E-ISSN 1743-2944, Vol. 34, no 9, p. 641-648Article in journal (Refereed) Published
Abstract [en]

Accelerated NVDA (VDA 233-102) tests were performed on bare Zn and Al sheets, Galfan coating (Zn-5 wt-% Al) and Galvalume coating (Zn-55 wt-% Al) on steel. ZnO, Zn(OH)(2) and Zn-5(OH)(8)Cl-2 center dot H2O were the main corrosion products identified on both bare Zn sheet and Galfan. AlOOH and Al(OH)(3) were preferentially formed on bare Al sheet and Galvalume. In addition, Zn-Al-containing corrosion products, Zn6Al2(OH)(16)CO3 center dot 4H(2)O and/or Zn2Al(OH)(6)Cl center dot 2H(2)O were identified on both Galfan and Galvalume. Corrosion products of Zn6Al2(OH)(16)CO3 center dot 4H(2)O with a platelet morphology were preferentially formed in the zinc-rich interdendritic regions of the Galvalume surface. Galfan revealed a similar corrosion behaviour as bare Zn sheet, whereas Galvalume exhibited similar behaviour as bare Al sheet. Deposition of chlorides highly influenced the corrosion of both Galvalume and Al rather than Galfan and Zn due to the rapid local damage of the compact native thin film of Al2O3.

Place, publisher, year, edition, pages
TAYLOR & FRANCIS LTD, 2018
Keywords
Atmospheric corrosion, NVDA tests, Zn, Al, Galfan, Galvalume, chloride, microstructure
National Category
Corrosion Engineering
Identifiers
urn:nbn:se:kth:diva-232426 (URN)10.1080/02670844.2017.1305658 (DOI)000437723800001 ()2-s2.0-85016451068 (Scopus ID)
Note

QC 20180724

Available from: 2018-07-24 Created: 2018-07-24 Last updated: 2018-07-24Bibliographically approved
Di Bucchianico, S., Gliga, A. R., Åkerlund, E., Skoglund, S., Odnevall Wallinder, I., Fadeel, B. & Karlsson, H. L. (2018). Calcium-dependent cyto- and genotoxicity of nickel metal and nickel oxide nanoparticles in human lung cells. Particle and Fibre Toxicology, 15, Article ID 32.
Open this publication in new window or tab >>Calcium-dependent cyto- and genotoxicity of nickel metal and nickel oxide nanoparticles in human lung cells
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2018 (English)In: Particle and Fibre Toxicology, ISSN 1743-8977, E-ISSN 1743-8977, Vol. 15, article id 32Article in journal (Refereed) Published
Abstract [en]

Background: Genotoxicity is an important toxicological endpoint due to the link to diseases such as cancer. Therefore, an increased understanding regarding genotoxicity and underlying mechanisms is needed for assessing the risk with exposure to nanoparticles (NPs). The aim of this study was to perform an in-depth investigation regarding the genotoxicity of well-characterized Ni and NiO NPs in human bronchial epithelial BEAS-2B cells and to discern possible mechanisms. Comparisons were made with NiCl2 in order to elucidate effects of ionic Ni. Methods: BEAS-2B cells were exposed to Ni and NiO NPs, as well as NiCl2, and uptake and cellular dose were investigated by transmission electron microscopy (TEM) and inductively coupled plasma mass spectrometry (ICP-MS). The NPs were characterized in terms of surface composition (X-ray photoelectron spectroscopy), agglomeration (photon cross correlation spectroscopy) and nickel release in cell medium (ICP-MS). Cell death (necrosis/apoptosis) was investigated by Annexin VFITC/PI staining and genotoxicity by cytokinesis-block micronucleus (cytome) assay (OECD 487), chromosomal aberration (OECD 473) and comet assay. The involvement of intracellular reactive oxygen species (ROS) and calcium was explored using the fluorescent probes, DCFH-DA and Fluo-4. Results: NPs were efficiently taken up by the BEAS-2B cells. In contrast, no or minor uptake was observed for ionic Ni from NiCl2. Despite differences in uptake, all exposures (NiO, Ni NPs and NiCl2) caused chromosomal damage. Furthermore, NiO NPs were most potent in causing DNA strand breaks and generating intracellular ROS. An increase in intracellular calcium was observed and modulation of intracellular calcium by using inhibitors and chelators clearly prevented the chromosomal damage. Chelation of iron also protected against induced damage, particularly for NiO and NiCl2. Conclusions: This study has revealed chromosomal damage by Ni and NiO NPs as well as Ni ionic species and provides novel evidence for a calcium-dependent mechanism of cyto- and genotoxicity.

Place, publisher, year, edition, pages
BMC, 2018
Keywords
Nickel/nickel oxide nanoparticles, Chromosomal aberrations, Endoreduplication, Calcium homeostasis, Carcinogenic potential
National Category
Pharmacology and Toxicology
Identifiers
urn:nbn:se:kth:diva-232767 (URN)10.1186/s12989-018-0268-y (DOI)000439340800001 ()30016969 (PubMedID)2-s2.0-85050147056 (Scopus ID)
Funder
Forte, Swedish Research Council for Health, Working Life and Welfare, 2011-0832Swedish Research Council, 2014-4598 2017-03931
Note

QC 20180803

Available from: 2018-08-03 Created: 2018-08-03 Last updated: 2018-08-06Bibliographically approved
Wei, Z., Edin, J., Karlsson, A. E., Petrovic, K., Soroka, I. L., Odnevall Wallinder, I. & Hedberg, Y. (2018). Can gamma irradiation during radiotherapy influence the metal release process for biomedical CoCrMo and 316L alloys?. Journal of Biomedical Materials Research. Part B - Applied biomaterials, 106(7), 2673-2680
Open this publication in new window or tab >>Can gamma irradiation during radiotherapy influence the metal release process for biomedical CoCrMo and 316L alloys?
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2018 (English)In: Journal of Biomedical Materials Research. Part B - Applied biomaterials, ISSN 1552-4973, E-ISSN 1552-4981, Vol. 106, no 7, p. 2673-2680Article in journal (Refereed) Published
Abstract [en]

The extent of metal release from implant materials that are irradiated during radiotherapy may be influenced by irradiation-formed radicals. The influence of gamma irradiation, with a total dose of relevance for radiotherapy (e.g., for cancer treatments) on the extent of metal release from biomedical stainless steel AISI 316L and a cobalt-chromium alloy (CoCrMo) was investigated in physiological relevant solutions (phosphate buffered saline with and without 10 g/L bovine serum albumin) at pH 7.3. Directly after irradiation, the released amounts of metals were significantly higher for irradiated CoCrMo as compared to nonirradiated CoCrMo, resulting in an increased surface passivation (enhanced passive conditions) that hindered further release. A similar effect was observed for 316L showing lower nickel release after 1 h of initially irradiated samples as compared to nonirradiated samples. However, the effect of irradiation (total dose of 16.5 Gy) on metal release and surface oxide composition and thickness was generally small. Most metals were released initially (within seconds) upon immersion from CoCrMo but not from 316L. Albumin induced an increased amount of released metals from AISI 316L but not from CoCrMo. Albumin was not found to aggregate to any greater extent either upon gamma irradiation or in the presence of trace metal ions, as determined using different light scattering techniques. Further studies should elucidate the effect of repeated friction and fractionated low irradiation doses on the short- and long term metal release process of biomedical materials.

Place, publisher, year, edition, pages
Wiley, 2018
Keywords
BSA, implant, passivation, radicals, radiotherapy
National Category
Occupational Health and Environmental Health Corrosion Engineering
Identifiers
urn:nbn:se:kth:diva-225956 (URN)10.1002/jbm.b.34084 (DOI)000445449800017 ()29424962 (PubMedID)2-s2.0-85041712415 (Scopus ID)
Funder
Swedish Research Council, 2015–04177Carl Tryggers foundation , CTS 15:353
Note

QC 20180611

Available from: 2018-04-11 Created: 2018-04-11 Last updated: 2018-10-22Bibliographically approved
Pradhan, S., Hedberg, J., Rosenqvist, J., Jonsson, C. M., Wold, S., Blomberg, E. & Odnevall Wallinder, I. (2018). Influence of humic acid and dihydroxy benzoic acid on the agglomeration, adsorption, sedimentation and dissolution of copper, manganese, aluminum and silica nanoparticles - A tentative exposure scenario. PLoS ONE, 13(2), Article ID e0192553.
Open this publication in new window or tab >>Influence of humic acid and dihydroxy benzoic acid on the agglomeration, adsorption, sedimentation and dissolution of copper, manganese, aluminum and silica nanoparticles - A tentative exposure scenario
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2018 (English)In: PLoS ONE, ISSN 1932-6203, E-ISSN 1932-6203, Vol. 13, no 2, article id e0192553Article in journal (Refereed) Published
Abstract [en]

This work focuses on kinetic aspects of stability, mobility, and dissolution of bare Cu, Al and Mn, and SiO2 NPs in synthetic freshwater (FW) with and without the presence of natural organic matter (NOM). This includes elucidation of particle and surface interactions, metal dissolution kinetics, and speciation predictions of released metals in solution. Dihydroxy benzoic acid (DHBA) and humic acid adsorbed rapidly on all metal NPs (< 1 min) via multiple surface coordinations, followed in general by rapid agglomeration and concomitant sedimentation for a large fraction of the particles. In contrast, NOM did not induce agglomeration of the SiO2 NPs during the test duration (21 days). DHBA in concentrations of 0.1 and 1 mM was unable to stabilize the metal NPs for time periods longer than 6 h, whereas humic acid, at certain concentrations (20 mg/L) was more efficient (> 24 h). The presence of NOM increased the amount of released metals into solution, in particular for Al and Cu, whereas the effect for Mn was minor. At least 10% of the particle mass was dissolved within 24 h and remained in solution for the metal NPs in the presence of NOM. Speciation modeling revealed that released Al and Cu predominantly formed complexes with NOM, whereas less complexation was seen for Mn. The results imply that potentially dispersed NPs of Cu, Al and Mn readily dissolve or sediment close to the source in freshwater of low salinity, whereas SiO2 NPs are more stable and therefore more mobile in solution.

Place, publisher, year, edition, pages
PUBLIC LIBRARY SCIENCE, 2018
National Category
Materials Engineering
Identifiers
urn:nbn:se:kth:diva-224031 (URN)10.1371/journal.pone.0192553 (DOI)000424517900091 ()2-s2.0-85041731628 (Scopus ID)
Note

QC 20180323

Available from: 2018-03-23 Created: 2018-03-23 Last updated: 2018-10-19Bibliographically approved
Lebedova, J., Hedberg, Y., Odnevall Wallinder, I. & Karlsson, H. L. (2018). Size-dependent genotoxicity of silver, gold and platinum nanoparticles studied using the mini-gel comet assay and micronucleus scoring with flow cytometry. Mutagenesis, 33(1), 77-85
Open this publication in new window or tab >>Size-dependent genotoxicity of silver, gold and platinum nanoparticles studied using the mini-gel comet assay and micronucleus scoring with flow cytometry
2018 (English)In: Mutagenesis, ISSN 0267-8357, E-ISSN 1464-3804, Vol. 33, no 1, p. 77-85Article in journal (Refereed) Published
Abstract [en]

Metallic nanoparticles (NPs) are promising nanomaterials used in different technological solutions as well as in consumer products. Silver (Ag), gold (Au) and platinum (Pt) represent three metallic NPs with current or suggested use in different applications. Pt is also used as vehicle exhaust catalyst leading to a possible exposure via inhalation. Despite their use, there is limited data on their genotoxic potential and possible size-dependent effects, particularly for Pt NPs. The aim of this study was to explore size-dependent genotoxicity of these NPs (5 and 50 nm) following exposure of human bronchial epithelial cells. We characterised the NPs and assessed the viability (Alamar blue assay), formation of DNA strand breaks (mini-gel comet assay) and induction of micronucleus (MN) analysed using flow cytometry (in vitro microflow kit). The results confirmed the primary size (5 and 50 nm) but showed agglomeration of all NPs in the serum free medium used. Slight reduced cell viability (tested up to 50 mu g/ml) was observed following exposure to the Ag NPs of both particle sizes as well as to the smallest (5 nm) Au NPs. Similarly, at non-cytotoxic concentrations, both 5 and 50 nm-sized Ag NPs, as well as 5 nm-sized Au NPs, increased DNA strand breaks whereas for Pt NPs only the 50 nm size caused a slight increase in DNA damage. No clear induction of MN was observed in any of the doses tested (up to 20 mu g/ml). Taken together, by using the comet assay our study shows DNA strand breaks induced by Ag NPs, without any obvious differences in size, whereas effects from Au and Pt NPs were size-dependent in the sense that the 5 nm-sized Au NPs and 50 nm-sized Pt NPs particles were active. No clear induction of MN was observed for the NPs.

Place, publisher, year, edition, pages
OXFORD UNIV PRESS, 2018
National Category
Pharmacology and Toxicology
Identifiers
urn:nbn:se:kth:diva-225329 (URN)10.1093/mutage/gex027 (DOI)000426079100011 ()2-s2.0-85042721477 (Scopus ID)
Note

QC 20180403

Available from: 2018-04-03 Created: 2018-04-03 Last updated: 2018-04-03Bibliographically approved
Mei, N., Belleville, L., Cha, Y., Olofsson, U., Odnevall Wallinder, I., Persson, K.-A. -. & Hedberg, Y. (2018). Size-separated particle fractions of stainless steel welding fume particles – A multi-analytical characterization focusing on surface oxide speciation and release of hexavalent chromium. Journal of Hazardous Materials, 342, 527-535
Open this publication in new window or tab >>Size-separated particle fractions of stainless steel welding fume particles – A multi-analytical characterization focusing on surface oxide speciation and release of hexavalent chromium
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2018 (English)In: Journal of Hazardous Materials, ISSN 0304-3894, E-ISSN 1873-3336, Vol. 342, p. 527-535Article in journal (Refereed) Published
Abstract [en]

Welding fume of stainless steels is potentially health hazardous. The aim of this study was to investigate the manganese (Mn) and chromium (Cr) speciation of welding fume particles and their extent of metal release relevant for an inhalation scenario, as a function of particle size, welding method (manual metal arc welding, metal arc welding using an active shielding gas), different electrodes (solid wires and flux-cored wires) and shielding gases, and base alloy (austenitic AISI 304L and duplex stainless steel LDX2101). Metal release investigations were performed in phosphate buffered saline (PBS), pH 7.3, 37°, 24 h. The particles were characterized by means of microscopic, spectroscopic, and electroanalytical methods. Cr was predominantly released from particles of the welding fume when exposed in PBS [3–96% of the total amount of Cr, of which up to 70% as Cr(VI)], followed by Mn, nickel, and iron. Duplex stainless steel welded with a flux-cored wire generated a welding fume that released most Cr(VI). Nano-sized particles released a significantly higher amount of nickel compared with micron-sized particle fractions. The welding fume did not contain any solitary known chromate compounds, but multi-elemental highly oxidized oxide(s) (iron, Cr, and Mn, possibly bismuth and silicon). 

Place, publisher, year, edition, pages
Elsevier, 2018
Keywords
Chromium(VI), Flux-cored wire, Manganese, Nickel, Welding
National Category
Materials Engineering
Identifiers
urn:nbn:se:kth:diva-216800 (URN)10.1016/j.jhazmat.2017.08.070 (DOI)000414880800057 ()28886565 (PubMedID)2-s2.0-85028707249 (Scopus ID)
Funder
VINNOVA, 2017-02519
Note

QC 20171205

Available from: 2017-11-14 Created: 2017-11-14 Last updated: 2017-12-05Bibliographically approved
Chang, T., Herting, G., Jin, Y., Leygraf, C. & Odnevall Wallinder, I. (2018). The golden alloy Cu5Zn5Al1Sn: Patina evolution in chloride-containing atmospheres. Corrosion Science, 133, 190-203
Open this publication in new window or tab >>The golden alloy Cu5Zn5Al1Sn: Patina evolution in chloride-containing atmospheres
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2018 (English)In: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 133, p. 190-203Article in journal (Refereed) Published
Abstract [en]

The influence of chloride deposition on the formation, evolution and barrier properties of the patina formed on CuSZn5Al1Sn used for architectural cladding is explored via long-term marine field exposures and laboratory investigations. The presence of Cu2O, ZnO, Al2O3 and SnO2 within the inner part of the patina and intercalation of SnO2, Zn-5(CO3)(2)(OH)(6), Zn6Al2(OH)(16)CO3 center dot 4H(2)O, Zn-5(OH)(8)Cl-2 center dot H2O within its outer part, predominantly composed of Cu-2(OH)(3)Cl, significantly reduce the chloride-induced corrosion compared with Cu metal. The intercalation of zinc-rich corrosion products within the patina and not at the top-surface explain their marginal influence on the runoff process that mainly occurs at the outmost surface.

Place, publisher, year, edition, pages
Elsevier, 2018
Keywords
Cu alloy, Atmospheric corrosion, runoff, Patina evolution, corrosion product characterization
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:kth:diva-226775 (URN)10.1016/j.corsci.2018.01.027 (DOI)000429764100018 ()2-s2.0-85041138972 (Scopus ID)
Note

QC 20180504

Available from: 2018-05-04 Created: 2018-05-04 Last updated: 2018-06-04Bibliographically approved
Hendriks, G., McCarrick, S., Cappellini, F., Derr, R., Hedberg, J., Odnevall Wallinder, I. & Karlsson, H. L. (2018). The ToxTracker assay as a tool for mechanism-based (geno) toxicity screening of nanoparticles and read across. Paper presented at 49th Annual Meeting of the Environmental-Mutagenesis-and-Genomics-Society (EMGS) - Maintaining Genomic Integrity in the Face of Environmental Insult, SEP 22-26, 2018, San Antonio, TX. Environmental and Molecular Mutagenesis, 59, 77-77
Open this publication in new window or tab >>The ToxTracker assay as a tool for mechanism-based (geno) toxicity screening of nanoparticles and read across
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2018 (English)In: Environmental and Molecular Mutagenesis, ISSN 0893-6692, E-ISSN 1098-2280, Vol. 59, p. 77-77Article in journal, Meeting abstract (Other academic) Published
Place, publisher, year, edition, pages
Wiley-VCH Verlagsgesellschaft, 2018
National Category
Environmental Sciences related to Agriculture and Land-use
Identifiers
urn:nbn:se:kth:diva-234573 (URN)000442847800109 ()
Conference
49th Annual Meeting of the Environmental-Mutagenesis-and-Genomics-Society (EMGS) - Maintaining Genomic Integrity in the Face of Environmental Insult, SEP 22-26, 2018, San Antonio, TX
Note

QC 20180917

Available from: 2018-09-17 Created: 2018-09-17 Last updated: 2018-09-17Bibliographically approved
Skoglund, S., Blomberg, E., Odnevall Wallinder, I., Grillo, I., Pedersen, J. S. & Bergström, L. M. (2017). A novel explanation for the enhanced colloidal stability of silver nanoparticles in the presence of an oppositely charged surfactant. Physical Chemistry, Chemical Physics - PCCP, 19(41), 28037-28043
Open this publication in new window or tab >>A novel explanation for the enhanced colloidal stability of silver nanoparticles in the presence of an oppositely charged surfactant
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2017 (English)In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 19, no 41, p. 28037-28043Article in journal (Refereed) Published
Abstract [en]

The structural behavior in aqueous mixtures of negatively charged silver nanoparticles (Ag NPs) together with the cationic surfactants cetyltrimethylammonium bromide (CTAB) and dodecyltrimethylammonium chloride (DTAC), respectively, has been investigated using SANS and SAXS. From our SANS data analysis we are able to conclude that the surfactants self-assemble into micellar clusters surrounding the Ag NPs. We are able to quantify our results by means of fitting experimental SANS data with a model based on cluster formation of micelles with very good agreement. Based on our experimental results, we propose a novel mechanism for the stabilization of negatively charged Ag NPs in a solution of positively charged surfactants in which cluster formation of micelles in the vicinity of the particles prevents the particles from aggregating. Complementary SAXS and DLS measurements further support this novel way of explaining stabilization of small hydrophilic nanoparticles in surfactant-containing solutions.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY, 2017
National Category
Chemical Sciences
Identifiers
urn:nbn:se:kth:diva-217409 (URN)10.1039/c7cp04662f (DOI)000413778800015 ()28994441 (PubMedID)2-s2.0-85032624124 (Scopus ID)
Note

QC 20171121

Available from: 2017-11-21 Created: 2017-11-21 Last updated: 2017-11-21Bibliographically approved
Leygraf, C., Chang, T., Odnevall Wallinder, I., De La Fuente, D., Chico, B., Diaz, I. & Morcillo, M. (2017). Analysis of historic copper patinas 1: Influence of substrate on patina uniformity. In: EUROCORR 2017 - The Annual Congress of the European Federation of Corrosion, 20th International Corrosion Congress and Process Safety Congress 2017: . Paper presented at Joint European Corrosion Congress 2017, EUROCORR 2017 and 20th International Corrosion Congress and Process Safety Congress 2017, Prague Congress Centre, Prague, Czech Republic, 3 September 2017 through 7 September 2017. Asociace koroznich inzenyru z.s.- AKI - Czech Association of Corrosion Engineers
Open this publication in new window or tab >>Analysis of historic copper patinas 1: Influence of substrate on patina uniformity
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2017 (English)In: EUROCORR 2017 - The Annual Congress of the European Federation of Corrosion, 20th International Corrosion Congress and Process Safety Congress 2017, Asociace koroznich inzenyru z.s.- AKI - Czech Association of Corrosion Engineers , 2017Conference paper, Published paper (Refereed)
Place, publisher, year, edition, pages
Asociace koroznich inzenyru z.s.- AKI - Czech Association of Corrosion Engineers, 2017
National Category
Other Chemistry Topics
Identifiers
urn:nbn:se:kth:diva-234516 (URN)2-s2.0-85052338861 (Scopus ID)
Conference
Joint European Corrosion Congress 2017, EUROCORR 2017 and 20th International Corrosion Congress and Process Safety Congress 2017, Prague Congress Centre, Prague, Czech Republic, 3 September 2017 through 7 September 2017
Note

QC 20180907

Available from: 2018-09-07 Created: 2018-09-07 Last updated: 2018-09-07Bibliographically approved
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ORCID iD: ORCID iD iconorcid.org/0000-0003-2206-0082

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