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Odnevall Wallinder, IngerORCID iD iconorcid.org/0000-0003-2206-0082
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Publications (10 of 189) Show all publications
Wang, X., Herting, G., Wei, Z., Odnevall Wallinder, I. & Hedberg, Y. (2019). Bioaccessibility of nickel and cobalt in powders and massive forms of stainless steel, nickel- or cobalt-based alloys, and nickel and cobalt metals in artificial sweat. Regulatory toxicology and pharmacology, 106, 15-26
Open this publication in new window or tab >>Bioaccessibility of nickel and cobalt in powders and massive forms of stainless steel, nickel- or cobalt-based alloys, and nickel and cobalt metals in artificial sweat
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2019 (English)In: Regulatory toxicology and pharmacology, ISSN 0273-2300, E-ISSN 1096-0295, Vol. 106, p. 15-26Article in journal (Refereed) Published
Abstract [en]

Nickel (Ni)and cobalt (Co)are the most common metal allergens upon skin contact at occupational settings and during consumer handling of metals and alloys. A standardized test (EN, 1811)exists to assess Ni release from articles of metals and alloys in massive forms intended for direct and prolonged skin contact, but no corresponding test exists for other materials such as powders or massive forms of alloys placed on the market or to determine the release of Co, for which only limited data is available. Differences in Ni and Co release from massive forms of a range of common stainless steels and some high-alloyed grades compared to Ni and Co metals were therefore assessed in artificial sweat for 1 week at 30 °C according to EN 1811. A comparable modified test procedure was elaborated and used for powders and some selected massive alloys. All alloys investigated released significantly less amount of Ni (100–5000-fold)and Co (200–400,000-fold)compared with Ni and Co metal, respectively. Almost all alloys showed a lower bioaccessible concentration (0.007–6.8 wt% Ni and 0.00003–0.6 wt% Co)when compared to corresponding bulk alloy contents (0.1–53 wt% Ni, 0.02–65 wt% Co). Observed differences are, among other factors, related to differences in bulk composition and to surface oxide characteristics. For the powders, less Ni and Co were released per surface area, but more per mass, compared to the corresponding massive forms. © 2019 The Authors

Place, publisher, year, edition, pages
Academic Press Inc., 2019
Keywords
Artificial sweat, Classification, Corrosion, EN 1811, Metal release, Particles, Regulation, Skin sensitizer, alloy, cobalt, dermatological agent, nickel, oxide, stainless steel, unclassified drug, Article, calibration, chemical composition, concentration (parameter), particle size, pH, powder, priority journal, surface area, surface property
National Category
Materials Chemistry
Identifiers
urn:nbn:se:kth:diva-252512 (URN)10.1016/j.yrtph.2019.04.017 (DOI)2-s2.0-85064756776 (Scopus ID)
Note

QC 20190710

Available from: 2019-07-10 Created: 2019-07-10 Last updated: 2019-07-10Bibliographically approved
Gupta, G. S., Gliga, A., Hedberg, J., Serra, A., Greco, D., Odnevall Wallinder, I. & Fadeel, B. (2019). Cobalt-impregnated tungsten nanoparticles and cobalt ions trigger toxicity in differentiating neuronal cells: potential link to parkinsonian neurodegeneration. Paper presented at 55th Congress of the European-Societies-of-Toxicology (EUROTOX) - Toxicology - Science Providing Solutions, SEP 08-11, 2019, Helsinki, FINLAND. Toxicology Letters, 314, S201-S202
Open this publication in new window or tab >>Cobalt-impregnated tungsten nanoparticles and cobalt ions trigger toxicity in differentiating neuronal cells: potential link to parkinsonian neurodegeneration
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2019 (English)In: Toxicology Letters, ISSN 0378-4274, E-ISSN 1879-3169, Vol. 314, p. S201-S202Article in journal, Meeting abstract (Other academic) Published
Place, publisher, year, edition, pages
ELSEVIER IRELAND LTD, 2019
National Category
Pharmacology and Toxicology
Identifiers
urn:nbn:se:kth:diva-260992 (URN)000484771800542 ()
Conference
55th Congress of the European-Societies-of-Toxicology (EUROTOX) - Toxicology - Science Providing Solutions, SEP 08-11, 2019, Helsinki, FINLAND
Note

QC 20191010

Available from: 2019-10-10 Created: 2019-10-10 Last updated: 2019-10-10Bibliographically approved
McCarrick, S., Wei, Z., Moelijker, N., Derr, R., Persson, K.-A., Hendriks, G., . . . Karlsson, H. L. (2019). High variability in toxicity of welding fume nanoparticles from stainless steel in lung cells and reporter cell lines: the role of particle reactivity and solubility. Nanotoxicology
Open this publication in new window or tab >>High variability in toxicity of welding fume nanoparticles from stainless steel in lung cells and reporter cell lines: the role of particle reactivity and solubility
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2019 (English)In: Nanotoxicology, ISSN 1743-5390, E-ISSN 1743-5404Article in journal (Refereed) Published
Abstract [en]

Millions of people in the world perform welding as their primary occupation resulting in exposure to metal-containing nanoparticles in the fumes generated. Even though health effects including airway diseases are well-known, there is currently a lack of studies investigating how different welding set-ups and conditions affect the toxicity of generated nanoparticles of the welding fume. The aim of this study was to investigate the toxicity of nine types of welding fume particles generated via active gas shielded metal arc welding (GMAW) of chromium-containing stainless steel under different conditions and, furthermore, to correlate the toxicity to the particle characteristics. Toxicological endpoints investigated were generation of reactive oxygen species (ROS), cytotoxicity, genotoxicity and activation of ToxTracker reporter cell lines. The results clearly underline that the choice of filler material has a large influence on the toxic potential. Fume particles generated by welding with the tested flux-cored wire (FCW) were found to be more cytotoxic compared to particles generated by welding with solid wire or metal-cored wire (MCW). FCW fume particles were also the most potent in causing ROS and DNA damage and they furthermore activated reporters related to DNA double- strand breaks and p53 signaling. Interestingly, the FCW fume particles were the most soluble in PBS, releasing more chromium in the hexavalent form and manganese compared to the other fumes. These results emphasize the importance of solubility of different metal constituents of the fume particles, rather than the total metal content, for their acute toxic potential.

Place, publisher, year, edition, pages
TAYLOR & FRANCIS LTD, 2019
Keywords
Welding, genotoxicity, ToxTracker, chromium(VI), manganese, metal release
National Category
Nano Technology
Identifiers
urn:nbn:se:kth:diva-257811 (URN)10.1080/17435390.2019.1650972 (DOI)000481646900001 ()31418618 (PubMedID)2-s2.0-85070998815 (Scopus ID)
Note

QC 20190906

Available from: 2019-09-06 Created: 2019-09-06 Last updated: 2019-10-02Bibliographically approved
Hedberg, J., Fransson, K., Prideaux, S., Roos, S., Jönsson, C. & Odnevall Wallinder, I. (2019). Improving the life cycle impact assessment of metal ecotoxicity: Importance of chromium speciation, water chemistry, and metal release. Sustainability, 11(6), Article ID 1655.
Open this publication in new window or tab >>Improving the life cycle impact assessment of metal ecotoxicity: Importance of chromium speciation, water chemistry, and metal release
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2019 (English)In: Sustainability, ISSN 2071-1050, E-ISSN 2071-1050, Vol. 11, no 6, article id 1655Article in journal (Refereed) Published
Abstract [en]

Investigations of metal ecotoxicity in life cycle assessment (LCA) and life cycle impact assessment (LCIA) are becoming important tools for evaluating the environmental impact of a product or process. There is, however, improvement needed for LCIA of metal ecotoxicity in order to make this assessment more relevant and robust. In this work, three issues within the LCIA of metal ecotoxicity are investigated, mainly focusing on topics related to stainless steel manufacturing. The first issue is the importance of considering regional water chemistry when constructing the characterization factor (CF). A model freshwater of relevance for stainless steel manufacturing in a region of Sweden was created with chemistry different from available options. The second issue is related to the lack of consideration on changes in speciation of Cr(VI) in freshwater for a given emission, as Cr(VI) to some extent will be reduced to Cr(III). Two new options are suggested based on relationships between the Cr(VI)-total Cr ratio as a way to improve the relevancy of LCIA for Cr(VI) in freshwater. The last issue is how to treat metal release from slags in LCIA. Metal release from slags was shown to vary significantly between different ways of modelling slag emissions (differences in total metal content, slag leaching tests, estimated emissions to groundwater). 

Place, publisher, year, edition, pages
MDPI AG, 2019
Keywords
Chromium, Chromium(VI), Ecotoxicity, Life cycle assessment, Life cycle impact assessment, Metal release, Nickel, Slag, Stainless steel, USEtox
National Category
Environmental Sciences
Identifiers
urn:nbn:se:kth:diva-252241 (URN)10.3390/su11061655 (DOI)000465613000110 ()2-s2.0-85063495702 (Scopus ID)
Note

QC20190612

Available from: 2019-06-12 Created: 2019-06-12 Last updated: 2019-06-12Bibliographically approved
Hedberg, J., Blomberg, E. & Odnevall Wallinder, I. (2019). In the Search for Nanospecific Effects of Dissolution of Metallic Nanoparticles at Freshwater-Like Conditions: A Critical Review. Environmental Science and Technology, 53(8), 4030-4044
Open this publication in new window or tab >>In the Search for Nanospecific Effects of Dissolution of Metallic Nanoparticles at Freshwater-Like Conditions: A Critical Review
2019 (English)In: Environmental Science and Technology, ISSN 0013-936X, E-ISSN 1520-5851, Vol. 53, no 8, p. 4030-4044Article in journal (Refereed) Published
Abstract [en]

Knowledge on relations between particle properties and dissolution/transformation characteristics of metal and metal oxide nanoparticles (NPs) in freshwater is important for risk assessment and product development. This critical review aims to elucidate nanospecific effects on dissolution of metallic NPs in freshwater and similar media. Dissolution rate constants are compiled and analyzed for NPs of silver (Ag), copper (Cu), copper oxide/hydroxide (CuO, Cu(OH) 2 ), zinc oxide (ZnO), manganese (Mn), and aluminum (Al), showing largely varying (orders of magnitude) constants when modeled using first order kinetics. An effect of small primary sizes (<15 nm) was observed, leading to increased dissolution rate constants and solubility in some cases. However, the often extensive particle agglomeration can result in reduced nanospecific effects on dissolution and also an increased uncertainty related to the surface area, a parameter that largely influence the extent of dissolution. Promising ways to model surface areas of NPs in solution using fractal dimensions and size distributions are discussed in addition to nanospecific aspects related to other processes such as corrosion, adsorption of natural organic matter (NOM), presence of capping agents, and existence of surface defects. The importance of the experimental design on the results of dissolution experiments of metal and metal oxide NPs is moreover highlighted, including the influence of ionic metal solubility and choice of particle dispersion methodology.

Place, publisher, year, edition, pages
American Chemical Society, 2019
Keywords
Biological materials, Copper oxides, Corrosion, Design of experiments, Dissolution, Fractal dimension, II-VI semiconductors, Metal nanoparticles, Rate constants, Risk assessment, Solubility, Surface defects, Water, Zinc oxide, First order kinetics, Metal and metal oxide nanoparticles, Metallic nanoparticles, Natural organic matters, Orders of magnitude, Particle agglomerations, Particle dispersion, Particle properties, Metals
National Category
Corrosion Engineering
Identifiers
urn:nbn:se:kth:diva-255914 (URN)10.1021/acs.est.8b05012 (DOI)2-s2.0-85064571562 (Scopus ID)
Note

QC 20190821

Available from: 2019-08-22 Created: 2019-08-22 Last updated: 2019-08-22Bibliographically approved
Hedberg, Y., Znidarsic, M., Herting, G., Milosev, I. & Odnevall Wallinder, I. (2019). Mechanistic insight on the combined effect of albumin and hydrogen peroxide on surface oxide composition and extent of metal release from Ti6Al4V. Journal of Biomedical Materials Research - Part B Applied Biomaterials, 107(3), 858-867
Open this publication in new window or tab >>Mechanistic insight on the combined effect of albumin and hydrogen peroxide on surface oxide composition and extent of metal release from Ti6Al4V
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2019 (English)In: Journal of Biomedical Materials Research - Part B Applied Biomaterials, ISSN 1552-4973, Vol. 107, no 3, p. 858-867Article in journal (Refereed) Published
Abstract [en]

The titanium–aluminium (6 wt%)–vanadium (4 wt%) (Ti6Al4V) alloy is widely used as an orthopedic and dental implant material due to its high corrosion resistance in such environments. The corrosion resistance is usually determined by means of electrochemical methods, which may not be able to detect other chemical surface reactions. Literature findings report a synergistic effect of the combination of the abundant protein albumin and hydrogen peroxide (H 2 O 2 ) on the extent of metal release and corrosion of Ti6Al4V. The objectives of this study were to gain further mechanistic insight on the interplay of H 2 O 2 and albumin on the metal release process of Ti6Al4V with special focus on (1) kinetics and (2) H 2 O 2 and albumin concentrations. This was accomplished mainly by metal release and surface oxide composition investigations, which confirmed the combined effect of H 2 O 2 and albumin on the metal release process, although not detectable by electrochemical open circuit potential measurements. A concentration of 30 mM H 2 O 2 induced substantial changes in the surface oxide characteristics, an oxide which became thicker and enriched in aluminum. Bovine serum albumin (BSA) seemed to be able to deplete this aluminum content from the outermost surface or at least to delay its surface enrichment. This effect increased with increased BSA concentration, and for time periods longer than 24 h. This study hence suggests that short-term (accelerated) corrosion resistance measurements are not sufficient to predict potential health effects of Ti6Al4V alloys since also chemical dissolution mechanisms play a large role for metal release, possibly in a synergistic way.

Place, publisher, year, edition, pages
WILEY, 2019
Keywords
implant, XPS, inflammation, complexation, dissolution
National Category
Other Materials Engineering
Identifiers
urn:nbn:se:kth:diva-248329 (URN)10.1002/jbm.b.34182 (DOI)000461683400040 ()30102828 (PubMedID)2-s2.0-85052655822 (Scopus ID)
Note

QC 20190409

Available from: 2019-04-09 Created: 2019-04-09 Last updated: 2019-04-09Bibliographically approved
Atapour, M., Wei, Z., Chaudhary, H., Lendel, C., Odnevall Wallinder, I. & Hedberg, Y. (2019). Metal release from stainless steel 316L in whey protein - And simulated milk solutions under static and stirring conditions. Food Control, 101, 163-172
Open this publication in new window or tab >>Metal release from stainless steel 316L in whey protein - And simulated milk solutions under static and stirring conditions
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2019 (English)In: Food Control, ISSN 0956-7135, E-ISSN 1873-7129, Vol. 101, p. 163-172Article in journal (Refereed) Published
Abstract [en]

Stainless steel is an important transport and processing contact material for bovine milk and dairy products. Release (migration) of metals, ions, complexes or wear debris/particles, and metal-induced protein aggregation in such environments are hence important to consider both from a corrosion and food safety perspective. This study aims on investigating the release of iron (Fe), chromium (Cr), and nickel (Ni) from AISI 316L stainless steel in contact with whey protein solutions relevant for protein drinks, and on how the whey proteins are influenced by stirring with a magnetic stir bar and metal release. Mechanistic insight is gained by parallel investigations of metal release from two reference non-protein containing solutions, a metal-complexing (citrate-containing) simulated milk solution (SMS) and a low complexing phosphate buffered saline solution (PBS). All immersion exposures were conducted at pH 6.8 for 0.5, 4, 24 and 48 hat room temperature at static and stirring conditions. All solutions and samples were investigated using different chemical, spectroscopic, microscopic, and electrochemical methods. Significantly higher amounts of Fe, Cr, and Ni were released into the whey protein solution (80 g/L) as compared to SMS and PBS. Strong enrichment of Cr in the surface oxide and reduction of the surface oxide thickness were associated with a higher amount of Ni release in the metal-complexing solutions (SMS and whey protein) compared with PBS. Stirring conditions resulted in higher amounts of metal release, enrichment of Cr in the surface oxide, and clear signs of wear of the 316L surface in all solutions compared to static conditions. The wear mechanism in the whey protein solution was different as compared to corresponding processes in SMS and PBS, involving an etching-like process and larger-sized wear debris. Electrochemical measurements at static conditions confirmed observed differences between the solutions, with the lowest corrosion resistance observed for coupons exposed in the whey protein solution, followed by SMS and PBS. Released metals in solution from the 316L coupons in contact with the whey protein solution resulted in enhanced rates of protein aggregation and precipitation of protein aggregates from solution. Further studies should be made to investigate other relevant test conditions and assess toxicological risks.

Place, publisher, year, edition, pages
ELSEVIER SCI LTD, 2019
Keywords
Protein, Whey, Stainless steel, Metal release, Food, Milk, Atomic absorption spectroscopy, X-ray photoelectron spectroscopy, Photon cross correlation spectroscopy, UV- visible spectroscopy, Scanning electron microscopy, Polarization resistance, Corrosion
National Category
Corrosion Engineering
Identifiers
urn:nbn:se:kth:diva-251269 (URN)10.1016/j.foodcont.2019.02.031 (DOI)000465049000023 ()2-s2.0-85063112841 (Scopus ID)
Note

QC 20190513

Available from: 2019-05-13 Created: 2019-05-13 Last updated: 2019-05-29Bibliographically approved
Leygraf, C., Chang, T., Herting, G. & Odnevall Wallinder, I. (2019). The origin and evolution of copper patina colour. Corrosion Science, 157, 337-346
Open this publication in new window or tab >>The origin and evolution of copper patina colour
2019 (English)In: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 157, p. 337-346Article in journal (Refereed) Published
Abstract [en]

The copper patina colour has been systematically explored through a large set of short- and long-term exposed copper metal samples. The initial brown-black appearance is attributed to semiconducting properties of cuprite (Cu2O) and fully attained at thickness 0.8 +/- 0.2 mu m. The characteristic green-blue appearance is due to the colour forming Cu(II)-ion in the outer patina layer which needs to be 12 +/- 2 mu m to fully cover the inner cuprite layer. No significant influence of atmospheric environment on patina colour is discerned. The green-blue patina colour on historic copper was attained after shorter exposures than in modem copper due to more inhomogeneous microstructure.

Place, publisher, year, edition, pages
Elsevier, 2019
Keywords
Copper, SEM, XPS, Atmospheric corrosion
National Category
Materials Engineering
Identifiers
urn:nbn:se:kth:diva-257434 (URN)10.1016/j.corsci.2019.05.025 (DOI)000480374200032 ()2-s2.0-85067466175 (Scopus ID)
Note

QC 20190902

Available from: 2019-09-02 Created: 2019-09-02 Last updated: 2019-09-02Bibliographically approved
Chang, T., Herting, G., Goidanich, S., Sánchez Amaya, J. M., Arenas, M. A., Le Bozec, N., . . . Odnevall Wallinder, I. (2019). The role of Sn on the long-term atmospheric corrosion of binary Cu-Sn bronze alloys in architecture. Corrosion Science, 149, 54-67
Open this publication in new window or tab >>The role of Sn on the long-term atmospheric corrosion of binary Cu-Sn bronze alloys in architecture
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2019 (English)In: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 149, p. 54-67Article in journal (Refereed) Published
Abstract [en]

The role of Sn on the atmospheric corrosion performance of binary Cu-Sn bronze alloys (4–6 wt.% Sn) compared with Cu metal used in outdoor architecture is elucidated in terms of microstructure, native surface oxide composition, patina evolution, corrosion rates, appearance and metal release. Results are presented for non-exposed surfaces and surfaces exposed at different urban and marine sites in Europe up to 5 years and based on multi-analytical findings from microscopic, spectroscopic, electrochemical and chemical investigations. Alloying influenced the corrosion, aesthetic appearance and patina evolution, differently for urban and marine sites, whereas no effects were observed on the release pattern.

Place, publisher, year, edition, pages
Elsevier, 2019
Keywords
Aesthetic appearance, Atmospheric corrosion, Bronze, Metal release, Patina
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:kth:diva-246467 (URN)10.1016/j.corsci.2019.01.002 (DOI)000459839700006 ()2-s2.0-85059532533 (Scopus ID)
Note

QC 20190328

Available from: 2019-03-28 Created: 2019-03-28 Last updated: 2019-03-28Bibliographically approved
Chang, T., Leygraf, C., Odnevall Wallinder, I. & Jin, Y. (2019). Understanding the Barrier Layer Formed via Adding BTAH in Copper Film Electrodeposition. Journal of the Electrochemical Society, 166(2), D10-D20
Open this publication in new window or tab >>Understanding the Barrier Layer Formed via Adding BTAH in Copper Film Electrodeposition
2019 (English)In: Journal of the Electrochemical Society, ISSN 0013-4651, E-ISSN 1945-7111, Vol. 166, no 2, p. D10-D20Article in journal (Refereed) Published
Abstract [en]

The influence of surface adsorption of benzotriazole (BTAH) and of chloride ions (Cl-) on the kinetics of copper electrodeposition/dissolution in copper sulfate solutions and on copper deposit characteristics have been investigated using electrochemical quartz crystal microbalance (EQCM) combined with cyclic voltammetry (CV). The addition of BTAH alone increases the overpotential of copper deposition, whereas a Cu(I)BTA complex forms at potentials higher than 0.08 V (vs. SCE) accompanied with the occurrence of copper anodic dissolution. With simultaneous addition of BTAH and Cl-, surface adsorption of Cl- competes with that of BTAH during the initial stage of copper nucleation. Different cuprous reaction intermediates form in the examined potential range -0.4 to 0.3 V (vs. SCE), which partly eliminate the favorable effect of BTAH on the deposited copper. A BTAH-containing adsorbed layer formed on the matte side of electrodeposited copper film in the presence of BTAH with or without Cl-, exhibiting a barrier surface property and an improved corrosion resistance compared with the copper film electrodeposited in the electrolyte without addition of BTAH.

Place, publisher, year, edition, pages
ELECTROCHEMICAL SOC INC, 2019
National Category
Materials Engineering
Identifiers
urn:nbn:se:kth:diva-241310 (URN)10.1149/2.0041902jes (DOI)000455193100001 ()
Note

QC 20190125

Available from: 2019-01-25 Created: 2019-01-25 Last updated: 2019-01-25Bibliographically approved
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ORCID iD: ORCID iD iconorcid.org/0000-0003-2206-0082

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