Open this publication in new window or tab >>2020 (English)In: Experimental mechanics, ISSN 0014-4851, E-ISSN 1741-2765, Vol. 60, p. 847-860Article in journal (Refereed) Published
Abstract [en]
Presently used experimental techniques for the characterization of tensile and compressive behavior of active layers in lithiumionbatteries have limitations of different kinds. This is particularly true for measurements of compressive properties.Furthermore, the characterizations of time-dependent stress-strain behavior are largely missing. In order to characterize thestress-strain relationship for a dry cathode active layer in lithium-ion batteries, a mechanical testing method is presented thatpreviously has been applied to the testing of optical fibers. The method is based on U-shaped bending of single-side coatedaluminum foils, which enables separate measurements of tensile and compressive properties. In particular, the method has clearadvantages for measurements of compressive properties in comparison to previously reported techniques. Relaxation experimentsare also conducted in order to characterize the time-dependent properties of the dry active layer and to check if these effectscould explain the measured hysteresis. It is found that the elastic modulus in compression is significantly larger than the elasticmodulus in tension and that the compressive modulus increases with strain level. Contrary, the tensile modulus is approximatelyindependent of strain. Furthermore, hysteresis effects are present at loading-unloading measurements, both for tension andcompression. The low values of the measured elastic moduli show that the electrode properties are largely controlled by thebinder and carbon additives. It is concluded that the development of particle-particle contacts most likely is the reason for thehigher modulus in compression in comparison to tension. The time-dependent effects are significant, primarily for shorter timescales, which explains the relaxation behavior, but they cannot fully explain the hysteresis effects. Most likely non-linear micromechanismsdo contribute as well.
Place, publisher, year, edition, pages
Springer, 2020
Keywords
Lithium-ion battery electrode .Constitutive properties . U-shape bending test .Time-dependent behavior .Hysteresis . FE simulation
National Category
Engineering and Technology
Research subject
Solid Mechanics
Identifiers
urn:nbn:se:kth:diva-282001 (URN)10.1007/s11340-020-00613-5 (DOI)000537390000001 ()2-s2.0-85086006308 (Scopus ID)
Funder
Swedish Energy Agency, 45387–1, 45514–1
Note
QC 20201021
2020-09-292020-09-292023-06-14Bibliographically approved