The world is facing a dramatic increase in the need for electricity and needs to battle the ever-increasing carbon dioxide emissions. New, more efficient, wide bandgap power electronics devices are developed to enable the urgent plans towards net-zero loss in electricity production, distribution and consumption. These devices will be very important pieces in the worldwide puzzle to enable fossil free electricity production, distribution and consumption. This paper discusses the status of wide bandgap device technology in the perspective of maturity of the devices for roll-out and implementation for industrial commercial use.

Photodetectors that convert light into electrical signals have become an indispensable element for a large number of technologies to enable extensive applications, ranging from optical communications to advanced imaging and motion detection, to automotive industry particularly including self-driving cars, and to astronomy and space exploration under harsh environment. The present photodetector market is predominated by silicon (CMOS-based) photodetectors. With the continuous growth of application areas, highly desired are photodetectors of higher performance in terms of speed, efficiency, detectable wavelength range, and integrability with semiconductor technology. These necessitate the development of new photodetectors based on special materials, rather than the conventional silicon single crystals, as building blocks for various advanced photodetection platforms. To this end, we summarize in this chapter the recent status of advanced photodetectors based on the emerging material, graphene. Our discussion includes the performance metrics, working mechanisms, practical implementation, as well as opportunities and challenges, for graphene-based photodetectors. 

The improvement of forming gas anneal (10 % H2 in N2) at 400 °C on electrical properties of Ge/GeOx/Tm2O3/HfO2 gate stacks is investigated. It is found that forming gas anneal effectively suppresses fixed charge density, oxide trap density and interface state density. Hydrogen is demonstrated to efficiently passivate the negative fixed charge density and reduce the global variability of the flatband voltage down to 90 mV over a wafer. A forming gas anneal is also found to reduce equivalent oxide thickness in scaled gate stacks.

The improvement of forming gas anneal (10 % H-2 in N-2) at 400 degrees C on electrical properties of Ge/GeOx/Tm2O3/HfO2 gate stacks is investigated. It is found that forming gas anneal effectively suppresses fixed charge density, oxide trap density and interface state density. Hydrogen is demonstrated to efficiently passivate the negative fixed charge density and reduce the global variability of the Hatband voltage down to 90 mV over a safer. A forming gas anneal is also found to reduce equivalent oxide thickness in scaled gate stacks.

An image sensor based on wide band gap silicon carbide (SiC) has the merits of high temperature operation and ultraviolet (UV) detection. To realize a SiC-based image sensor the challenge of opto-electronic on-chip integration of SiC photodetectors and digital electronic circuits must be addressed. Here, we demonstrate a novel SiC image sensor based on our in-house bipolar technology. The sensing part has 256 ( $16\times 16$ ) pixels. The digital circuit part for row and column selection contains two 4-to-16 decoders and one 8-bit counter. The digital circuits are designed in transistor-transistor logic (TTL). The entire circuit has 1959 transistors. It is the first demonstration of SiC opto-electronic on-chip integration. The function of the image sensor up to 400 degrees C has been verified by taking photos of the spatial patterns masked from UV light. The image sensor would play a significant role in UV photography, which has important applications in astronomy, clinics, combustion detection and art.

Graphene's unparalleled strength, chemical stability, ultimate surface-to-volume ratio and excellent electronic properties make it an ideal candidate as a material for membranes in micro- and nanoelectromechanical systems (MEMS and NEMS). However, the integration of graphene into MEMS or NEMS devices and suspended structures such as proof masses on graphene membranes raises several technological challenges, including collapse and rupture of the graphene. We have developed a robust route for realizing membranes made of double-layer CVD graphene and suspending large silicon proof masses on membranes with high yields. We have demonstrated the manufacture of square graphene membranes with side lengths from 7 mu m to 110 mu m, and suspended proof masses consisting of solid silicon cubes that are from 5 mu mx5 mu mx16.4 mu m to 100 mu mx100 mu mx16.4 mu m in size. Our approach is compatible with wafer-scale MEMS and semiconductor manufacturing technologies, and the manufacturing yields of the graphene membranes with suspended proof masses were >90%, with >70% of the graphene membranes having >90% graphene area without visible defects. The measured resonance frequencies of the realized structures ranged from tens to hundreds of kHz, with quality factors ranging from 63 to 148. The graphene membranes with suspended proof masses were extremely robust, and were able to withstand indentation forces from an atomic force microscope (AFM) tip of up to 7000nN. The proposed approach for the reliable and large-scale manufacture of graphene membranes with suspended proof masses will enable the development and study of innovative NEMS devices with new functionalities and improved performances.

In this work we study the epitaxial Si growth with Si2H6 for Ge surface passivation in CMOS devices. The Si-caps are grown on Ge in the hydrogen desorption limited regime at a nominal temperature of 400 degrees C. We evaluate the process window for the interface state density and show that there is an optimal Si-cap thickness between 8 and 9 monolayers for D-it < 510(11) cm(-2) eV(-1). Moreover, we discuss the strong impact of the Si-cap growth time and temperature on the interface state density, which arises from the Si thickness dependence on these growth parameters. Furthermore, we successfully transfer a TmSiO/Tm2O3/HfO2 gate stack process from Si to Ge devices with optimized Si-cap, yielding interface state density of 310(11) eV(-1) cm(-2) and a significant improvement in oxide trap density compared to GeOx passivation.

Epitaxial in situ doped Si0.73Ge0.27 alloys were grown selectively on patterned bulk Ge and bulk Si wafers. Si0.73Ge0.27 layers with a surface roughness of less than 3 nm were demonstrated. Selectively grown p+Si0.73Ge0.27 layers exhibited a resistivity of 3.5 mΩcm at a dopant concentration of 2.5 × 1019 boron atoms/cm3. P+/n diodes were fabricated by selectively growing p+-Si0.73Ge0.27 on n-doped bulk Ge and n-doped Si wafers, respectively. The geometrical leakage current contribution shifts from the perimeter to the bulk as the diode sizes increase. Extracted near midgap activation energies are similar to p+/n Ge junctions formed by ion implantation. This indicates that the reverse leakage current in p+/n Ge diodes fabricated with various doping methods, could originate from the same trap-assisted mechanism. Working p+/n diodes on Ge bulk substrates displayed a reverse current density as low as 2.2·10−2 A/cm2 which was found to be comparable to other literature data. The layers developed in this work can be used as an alternative method to form p+/n junctions on Ge substrates, showing comparable junction leakage results to ion implantation approaches.

Ultra-thin epitaxially grown Si layers have been used for Ge surface passivation in CMOS devices utilizing standard silicon SiO2/HfO2 gate stack. In this work, we propose a high-k TmSiO interfacial layer, which has shown excellent performance on Si, instead of the chemical SiO2. We successfully transfer a TmSiO/Tm2O3/HfO2 gate stack from silicon to Si-passivated Ge devices, yielding interface state density of 3·1011 eV-1cm-2, which is comparable to GeOx passivation. Moreover, Si-capped Ge gates with TmSiO interfacial layer achieve significant improvement in oxide trap density compared to GeOx passivation, exhibiting a potential for superior reliability. We further investigate the robustness of Si layer growth process and show that small (±3 °C) variations of growth temperature can be detrimental to the interface state density of the gate stacks.

Low-parasitic-capacitance 4H-SiC pMOSFETs were demonstrated for high-frequency CMOS inverters. In these pMOSFETs, device characteristics including parasitic capacitances (gate-source, gate-drain capacitance) were investigated and low parasitic capacitance was achieved by the trench gate structure.