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Iron-Based Molecular Water Oxidation Catalysts: Abundant, Cheap, and Promising
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Organic chemistry.
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry.ORCID iD: 0000-0002-4093-1251
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry.ORCID iD: 0000-0002-4521-2870
2019 (English)In: Chemistry - An Asian Journal, ISSN 1861-4728, E-ISSN 1861-471X, Vol. 14, no 1, p. 31-43Article, review/survey (Refereed) Published
Abstract [en]

An efficient and robust water oxidation catalyst based on abundant and cheap materials is the key to converting solar energy into fuels through artificial photosynthesis for the future of humans. The development of molecular water oxidation catalysts (MWOCs) is a smart way to achieve promising catalytic activity, thanks to the clear structures and catalytic mechanisms of molecular catalysts. Efficient MWOCs based on noble-metal complexes, for example, ruthenium and iridium, have been well developed over the last 30 years; however, the development of earth-abundant metal-based MWOCs is very limited and still challenging. Herein, the promising prospect of iron-based MWOCs is highlighted, with a comprehensive summary of previously reported studies and future research focus in this area.

Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH , 2019. Vol. 14, no 1, p. 31-43
Keywords [en]
artificial photosynthesis, electrochemistry, iron, molecular catalysts, oxidation, water splitting
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-241314DOI: 10.1002/asia.201801253ISI: 000454953700003PubMedID: 30362258Scopus ID: 2-s2.0-85057257052OAI: oai:DiVA.org:kth-241314DiVA, id: diva2:1282557
Note

QC 20190125

Available from: 2019-01-25 Created: 2019-01-25 Last updated: 2019-01-25Bibliographically approved

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Liu, TianqiZhang, BiaobiaoSun, Licheng

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