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Exploring the physicochemical and rheological properties of sustainable asphalt binders modified with lignin and high-viscosity additive
KTH, School of Architecture and the Built Environment (ABE), Civil and Architectural Engineering, Road and Railway Engineering. School of Highway, Chang'an University, South 2nd Ring Road Middle Section, Xi'an, Shaanxi, China.ORCID iD: 0000-0002-2694-6211
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.ORCID iD: 0000-0003-3375-352X
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Wood Chemistry and Pulp Technology.ORCID iD: 0000-0001-7433-0350
KTH, School of Architecture and the Built Environment (ABE), Civil and Architectural Engineering, Road and Railway Engineering.ORCID iD: 0000-0003-3968-6778
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2024 (English)In: Construction and Building Materials, ISSN 0950-0618, E-ISSN 1879-0526, Vol. 450, article id 138621Article in journal (Refereed) Published
Abstract [en]

The primary objective of this investigation is to evaluate how the incorporation of lignin and high-viscosity modifiers impacts the performance of asphalt binders. Lignin-modified asphalt binder (LBA) and lignin-high viscosity modifier composite-modified asphalt binder (LHA) were created by blending 5 % and 15 % lignin, respectively. To understand the physicochemical interactions, Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC) were employed to analyze functional groups, thermal properties, and phase changes. Additionally, the linear rheological behavior and nonlinear rheological behavior were evaluated through frequency sweep and multiple stress creep recovery tests. The findings suggest that lignin blends physically with the asphalt binder and high-viscosity modifier without a chemical reaction. Although the onset pyrolysis temperature of lignin is significantly lower than that of asphalt binders, due to its relatively low content, the thermal decomposition of lignin-modified asphalt binders is primarily controlled by the asphalt binder itself and still exceeds the construction temperature. However, lignin incorporation increases the asphalt binder's glass transition temperature, potentially affecting low-temperature performance. Lignin significantly enhances the modulus in the high-frequency region of both unmodified and high-viscosity modified asphalt binder. However, it has a negative effect on the modulus in the low-frequency region of high-viscosity modified asphalt binder. Furthermore, nonlinear creep recovery test results demonstrate that lignin positively contributes to the deformation resistance of unmodified asphalt binder in a content-dependent manner, whereas it reduces the elastic behavior and deformation resistance of high-viscosity modified asphalt binder. In addition, low levels of lignin increase the stress sensitivity of binders, while high levels of lignin decrease it. Despite these effects, the performance of lignin and high-viscosity additive composite-modified asphalt binder remains superior to that of unmodified asphalt binder. These findings offer valuable insights into the combined use of lignin and polymers in asphalt binder modification.

Place, publisher, year, edition, pages
Elsevier BV , 2024. Vol. 450, article id 138621
Keywords [en]
Asphalt binder, Chemical property, Lignin, Polymer, Rheological behavior
National Category
Infrastructure Engineering Other Materials Engineering
Identifiers
URN: urn:nbn:se:kth:diva-354895DOI: 10.1016/j.conbuildmat.2024.138621ISI: 001331890200001Scopus ID: 2-s2.0-85205711846OAI: oai:DiVA.org:kth-354895DiVA, id: diva2:1906224
Note

QC 20241029

Available from: 2024-10-16 Created: 2024-10-16 Last updated: 2024-10-29Bibliographically approved

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Li, HuisiSevastyanova, OlenaKringos, NicoleCavalli, Maria Chiara

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Wu, WangjieLi, HuisiSevastyanova, OlenaKringos, NicoleCavalli, Maria Chiara
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