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Nucleophilic Attack of Hydroxide on a Mn-V Oxo Complex: A Model of the O-O Bond Formation in the Oxygen Evolving Complex of Photosystem II
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology, Applied Electrochemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0002-4521-2870
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2009 (English)In: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 131, no 25, p. 8726-+Article in journal (Refereed) Published
Abstract [en]

A manganese(III) corrole complex, 1, has been synthesized and used to study a potential mechanism for oxidation of water to molecular oxygen. Oxidation by t-BuOOH gave the Mn-V=O complex 2. Addition of hydroxide Led to release of oxygen via the Mn-IV complex 4 and regeneration of complex 1. It could be shown that the oxygen from O-18-labeted water was incorporated in both the formed molecular oxygen and the peroxy intermediate 4.

Place, publisher, year, edition, pages
2009. Vol. 131, no 25, p. 8726-+
Keywords [en]
photosynthetic water oxidation, oxomanganese(v) porphyrin, manganese, corroles, compound-i, evolution, spectroscopy, peroxidase, catalysis
Identifiers
URN: urn:nbn:se:kth:diva-18568DOI: 10.1021/ja901139rISI: 000267631000004PubMedID: 19496534Scopus ID: 2-s2.0-67649610433OAI: oai:DiVA.org:kth-18568DiVA, id: diva2:336615
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2022-06-25Bibliographically approved

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Sun, Licheng

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