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Investigation of the kinetics of reduction of manganese tungstate by hydrogen
KTH, Superseded Departments (pre-2005), Materials Science and Engineering.ORCID iD: 0000-0002-3548-8638
KTH, Superseded Departments (pre-2005), Materials Science and Engineering.ORCID iD: 0000-0003-4695-9308
2000 (English)In: Scandinavian journal of metallurgy, ISSN 0371-0459, E-ISSN 1600-0692, Vol. 29, no 4, p. 151-155Article in journal (Refereed) Published
Abstract [en]

The present work was carried out as a part of a research program studying the reduction kinetics of some transition metal tungstates. Manganese tungstate was reduced by hydrogen under isothermal conditions in the temperature range 883-1183 K. The reaction was round to take place in a single step with MnO and W as the solid products. The activation energy for the reduction of manganese tungstate was evaluated to be 92 kJ mol(-1) using the initial reaction rates. This activation energy was compared with the activation energies of the other transition metal tungstates in the light of bond strength of the metal-oxygen bonds.

Place, publisher, year, edition, pages
2000. Vol. 29, no 4, p. 151-155
Keywords [en]
reduction, tungstate, kinetics, hydrogen, nonisothermal thermogravimetric method, metallic oxides
Identifiers
URN: urn:nbn:se:kth:diva-19866DOI: 10.1034/j.1600-0692.2000.d01-18.xISI: 000087955400003Scopus ID: 2-s2.0-0033723143OAI: oai:DiVA.org:kth-19866DiVA, id: diva2:338558
Note
QC 20100525Available from: 2010-08-10 Created: 2010-08-10 Last updated: 2022-09-08Bibliographically approved

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Sichen, Du

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