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Across the Board: Licheng Sun on the Mechanism of O-O Bond Formation in Photosystem II
KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Kemi.ORCID-id: 0000-0002-4093-1251
KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD. KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Kemi, Organisk kemi. Dalian Univ Technol.ORCID-id: 0000-0002-4521-2870
2019 (engelsk)Inngår i: ChemSusChem, ISSN 1864-5631, E-ISSN 1864-564X, Vol. 12, nr 14, s. 3401-3404Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

In this series of articles, the board members of ChemSusChem discuss recent research articles that they consider of exceptional quality and importance for sustainability. This entry features Prof. L. Sun, who proposes a special mechanism for O-O bond formation in photosystem II with involvement of an Mn-VII-oxo species induced by charge- and structural rearrangements. In this viewpoint, Proton transfer is involved in changes of the first coordination spheres around the Mn-VII-oxo site on the dangling Mn4 with de- and re-coordination of carboxylates (Glu333 and Asp170).

sted, utgiver, år, opplag, sider
WILEY-V C H VERLAG GMBH , 2019. Vol. 12, nr 14, s. 3401-3404
Emneord [en]
disproportionation, oxygen evolution, photosystem II, structural rearrangement, water splitting
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Identifikatorer
URN: urn:nbn:se:kth:diva-257575DOI: 10.1002/cssc.201901438ISI: 000478633900023PubMedID: 31240851Scopus ID: 2-s2.0-85068351514OAI: oai:DiVA.org:kth-257575DiVA, id: diva2:1353362
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QC 20190923

Tilgjengelig fra: 2019-09-23 Laget: 2019-09-23 Sist oppdatert: 2019-09-23bibliografisk kontrollert

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