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Homogeneous Oxidation of Water by Iron Complexes with Macrocyclic Ligands
Vise andre og tillknytning
2014 (engelsk)Inngår i: Chemistry - An Asian Journal, ISSN 1861-4728, E-ISSN 1861-471X, Vol. 9, nr 6, s. 1515-1518Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The activity of eleven separated iron complexes and nine in situ-generated iron complexes towards catalytic water oxidation have been examined in aqueous solutions with Ce(NH4)(2)(NO3)(6) as the oxidant. Two iron complexes bearing tridentate and tetradentate macrocyclic ligands were found to be novel water oxidation catalysts. The one with tetradentate ligand exhibited a promising activity with a turnover number of 65 for oxygen evolution.

sted, utgiver, år, opplag, sider
2014. Vol. 9, nr 6, s. 1515-1518
Emneord [en]
homogeneous catalysis, iron complex, oxygen evolution, renewable resources, water splitting
HSV kategori
Identifikatorer
URN: urn:nbn:se:kth:diva-147023DOI: 10.1002/asia.201400066ISI: 000336248900007Scopus ID: 2-s2.0-84901187858OAI: oai:DiVA.org:kth-147023DiVA, id: diva2:728428
Forskningsfinansiär
Swedish Energy AgencySwedish Research CouncilKnut and Alice Wallenberg Foundation
Merknad

QC 20140624

Tilgjengelig fra: 2014-06-24 Laget: 2014-06-23 Sist oppdatert: 2017-12-05bibliografisk kontrollert

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