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Glycerol-Modified Binary Layered Double Hydroxide Nanocomposites for Uranium Immobilization via Extended X-ray Absorption Fine Structure Technique and Density Functional Theory Calculation
Vise andre og tillknytning
2017 (engelsk)Inngår i: ACS SUSTAINABLE CHEMISTRY & ENGINEERING, ISSN 2168-0485, Vol. 5, nr 4, s. 3583-3595Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Novel, efficient, glycerol-modified nanoscale layered double hydroxides (rods Ca/Al LDH-Gl and flocculent Ni/Al LDH-Gl) were successfully synthesized by a simple one-step hydrothermal synthesis route and showed excellent adsorption capacities for U(VI) from aqueous solutions under various environmental conditions. The advanced spectroscopy analysis confirmed the existence of abundant oxygen-containing functional groups (e.g., C-O, O-C=O, and C=O) on the surfaces of Ca/AI LDH-Gl and Ni/Al LDH-Gl, which could provide enough free active sites for the binding of U(VI). The maximum adsorption capacities of Macro-application (Environment U(VI) calculated from the Sips model were 266.5 mg.g(-1) for Ca/Al LDH-Gl and 142.3 mg.g(-1) for Ni/Al LDH-Gl at 298.15 K, and the higher adsorption capacity of Ca/Al LDH-Gl might be due to more functional groups and abundant high-activity "Ca-O" groups. Macroscopic experiments proved that the interaction of U(VI) on Ca/Al LDH-Gl and Ni/Al LDH-Gl was due to surface complexation and electrostatic interactions. The extended Xray absorption fine structure analysis confirmed that U(IV) did not transformation to U(VI) on solid particles, and stable inner sphere complexes were not formed by reduction interaction but by chemical adsorption. The density functional theory (DFT) calculations further evidenced that the higher adsorption energies (i.e., E-ad = 4.00 eV for Ca/AI LDH-Gl-UO22+ and E-ad = 2.43 eV for Ca/Al LDH-Gl-UO2CO3) were mainly attributed to stronger hydrogen bonds and electrostatic interactions. The superior immobilization performance of Ca/AI LDH-Gl supports a potential strategy for decontamination of UO22+ from wastewater, and it may provide new insights for the efficient removal of radionuclides in environmental pollution cleanup.

sted, utgiver, år, opplag, sider
AMER CHEMICAL SOC , 2017. Vol. 5, nr 4, s. 3583-3595
Emneord [en]
Nanocomposites, Layered double hydroxides, Immobilization, U(VI), EXAFS
HSV kategori
Identifikatorer
URN: urn:nbn:se:kth:diva-206255DOI: 10.1021/acssuschemeng.7b00439ISI: 000398429700088Scopus ID: 2-s2.0-85016790731OAI: oai:DiVA.org:kth-206255DiVA, id: diva2:1095298
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QC 20170512

Tilgjengelig fra: 2017-05-12 Laget: 2017-05-12 Sist oppdatert: 2017-06-30bibliografisk kontrollert

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