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A fluorescent photochromic diarylethene based on naphthalic anhydride with strong solvatochromism
KTH, Skolan för bioteknologi (BIO), Teoretisk kemi och biologi.
2017 (engelsk)Inngår i: RSC Advances, E-ISSN 2046-2069, Vol. 7, nr 47, s. 29854-29859Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

A novel "push-pull" diarylethene molecule consisting of an electron withdrawing ethene bridge (1,8-naphthalic anhydride) and two moderate electron donating side chains (2,5-dimethylthiophene) has been designed and synthesized. The photochromism study, together with density functional theory calculations, revealed that the molecule exhibits reversible fluorescence switching capacity upon photo-isomerization and remarkable solvatochromism with red shift of the fluorescence maximum by more than 150 nm owing to intramolecular charge transfer.

sted, utgiver, år, opplag, sider
Royal Society of Chemistry, 2017. Vol. 7, nr 47, s. 29854-29859
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URN: urn:nbn:se:kth:diva-216767DOI: 10.1039/c7ra05157cISI: 000403320500069Scopus ID: 2-s2.0-85021676945OAI: oai:DiVA.org:kth-216767DiVA, id: diva2:1152277
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QC 20171024

Tilgjengelig fra: 2017-10-24 Laget: 2017-10-24 Sist oppdatert: 2024-03-18bibliografisk kontrollert

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