Endre søk
RefereraExporteraLink to record
Permanent link

Direct link
Referera
Referensformat
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf
Adsorption of poly(ethylene oxide)-b-poly(is an element of-caprolactone) copolymers at the silica-water interface
KTH, Skolan för kemivetenskap (CHE), Kemi, Ytkemi.
Vise andre og tillknytning
2005 (engelsk)Inngår i: Langmuir, ISSN 0743-7463, E-ISSN 1520-5827, Vol. 21, nr 7, 2930-2940 s.Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The adsorption of amphiphilic poly(ethylene oxide)-b-poly(epsilon-caprolactone) and poly(ethylene oxide)-b-poly(gamma-methyl-epsilon-caprolactone) copolymers in aqueous solution on silica and glass surfaces has been investigated by flow microcalorimetry, small-angle neutron scattering (SANS), surface forces, and complementary techniques. The studied copolymers consist of a poly(ethylene oxide) (PEO) block of M-n, = 5000 and a hydrophobic polyester block of poly(E-caprolactone) (PCL) or poly(gamma-methyl-epsilon-caprolactone) (PMCL) of M-n in the 950-2200 range. Compared to homoPEO, the adsorption of the copolymers is significantly increased by the connection of PEO to an aliphatic polyester block. According to calorimetric experiments, the copolymers interact with the surface mainly through the hydrophilic block. At low surface coverage, the PEO block interacts with the surface such that both PEO and PCL chains are exposed to the aqueous solution. At high surface coverage, a dense copolymer layer is observed with the PEO blocks oriented toward the solution. The structure of the copolymer layer has been analyzed by neutron scattering using the contrast matching technique and by tapping mode atomic force microscopy. The experimental observations agree with the coadsorption of micelles and free copolymer chains at the interface.

sted, utgiver, år, opplag, sider
2005. Vol. 21, nr 7, 2930-2940 s.
Emneord [en]
aqueous-solution, diblock copolymers, block-copolymers, nonionic surfactants, poly(caprolactone-b-ethylene oxide-b-caprolactone), competitive adsorption, hydrophobic surfaces, triblock copolymers, ethylene-oxide, kinetics
Identifikatorer
URN: urn:nbn:se:kth:diva-14647DOI: 10.1021/la047425+ISI: 000228042400046Scopus ID: 2-s2.0-16244416879OAI: oai:DiVA.org:kth-14647DiVA: diva2:332688
Merknad
QC 20100525Tilgjengelig fra: 2010-08-05 Laget: 2010-08-05 Sist oppdatert: 2017-12-12bibliografisk kontrollert

Open Access i DiVA

Fulltekst mangler

Andre lenker

Forlagets fulltekstScopus

Søk i DiVA

Av forfatter/redaktør
Claesson, Per M.
Av organisasjonen
I samme tidsskrift
Langmuir

Søk utenfor DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric

doi
urn-nbn
Totalt: 30 treff
RefereraExporteraLink to record
Permanent link

Direct link
Referera
Referensformat
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf