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Bidentate phosphine ligand based Fe2S2-containing macromolecules: Synthesis, characterization, and catalytic electrochemical hydrogen production
KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.ORCID-id: 0000-0002-4521-2870
2006 (engelsk)Inngår i: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 45, nr 23, s. 9169-9171Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The reaction of [Fe-2(CO)(6)(mu-SCH2)(2)NCH2CH2N(mu-SCH2)(2)Fe-2(CO)(6)] (1) with 1,2-bis(diphenylphosphino) ethane in the presence of Me3NO, 2H(2)O affords two structurally different metallomacromolecules: a dimer of the type [{Fe-2(CO)(5)(mu-SCH2)(2)NCH2CH2N(mu-SCH2) Fe-2(2)(CO)(5)}(Ph2PCH2)(2)] (2) and a tetramer species containing eight iron centers with an overall formula of [{Fe-2(CO)(6)(mu-SCH2)(2)NCH2CH2N( mu-SCH2)(2)Fe-2(CO)(5)}(2)(Ph2PCH2)(2)] (3). Their structures have been determined by X-ray crystallography, showing one macrocyclic complex (2) and one linear complex (3). Electrochemical hydrogen evolution catalyzed by these two complexes with ca. 80-90 single-run turnovers is observed, indicating good potential as catalysts for future applications.

sted, utgiver, år, opplag, sider
2006. Vol. 45, nr 23, s. 9169-9171
Emneord [en]
fe-only hydrogenases, active-site models, functional models, evolution
Identifikatorer
URN: urn:nbn:se:kth:diva-16110DOI: 10.1021/ic061258eISI: 000241778900008Scopus ID: 2-s2.0-33751280975OAI: oai:DiVA.org:kth-16110DiVA, id: diva2:334152
Merknad
QC 20100525Tilgjengelig fra: 2010-08-05 Laget: 2010-08-05 Sist oppdatert: 2017-12-12bibliografisk kontrollert

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