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Syntheses and crystal structures of new palladium(II) and platinum(IV) trialkylsulfonium compounds
KTH, Skolan för kemivetenskap (CHE), Kemi, Oorganisk kemi.
KTH, Skolan för kemivetenskap (CHE), Kemi, Oorganisk kemi.
KTH, Skolan för kemivetenskap (CHE), Kemi, Oorganisk kemi.
2007 (engelsk)Inngår i: Zeitschrift für Anorganische und Allgemeines Chemie, ISSN 0044-2313, E-ISSN 1521-3749, Vol. 633, nr 4, s. 643-646Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The reactions of platinum(II) iodide with triethyl- or trimethylsulfonium iodide in acetonitrile solution lead to the formation of crystalline products (Et3S)(2)[PtI6] (1) and [Me3S]=[PtI6]center dot CH3CN (2), respectively. The formation of Pt(IV) complexes may be explained either by disproportionation of PtI2 or oxidation by oxygen. Palladium(II) iodide reacts with triethylsulfonium iodide to give the palladium(II) complex (Et3S)(2)[PdI4] (3). The crystal structures of 1-3 were determined by single-crystal X-ray diffraction. In the crystal structures, the compounds 2 and 3 exhibit an extensive hydrogen-bonding network.

sted, utgiver, år, opplag, sider
2007. Vol. 633, nr 4, s. 643-646
Emneord [en]
platinum, palladium, sulfonium, ionic liquid, crystal structure, nanocrystalline solar-cells, ionic liquids, electrolytes, molten, polyiodides, complexes, iodides, salts
Identifikatorer
URN: urn:nbn:se:kth:diva-16484DOI: 10.1002/zaac.200600391ISI: 000245182100024Scopus ID: 2-s2.0-33947575961OAI: oai:DiVA.org:kth-16484DiVA, id: diva2:334526
Merknad
QC 20100525Tilgjengelig fra: 2010-08-05 Laget: 2010-08-05 Sist oppdatert: 2017-12-12bibliografisk kontrollert

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Gorlov, MikhailFischer, AndreasKloo, Lars A.
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