Endre søk
RefereraExporteraLink to record
Permanent link

Direct link
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf
Intermolecular electron transfer from photogenerated Ru(bpy)(3)(+) to 2Fe2S model complexes of the iron-only hydrogenase active site
KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.ORCID-id: 0000-0002-4521-2870
2007 (engelsk)Inngår i: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 46, nr 10, s. 3813-3815Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Visible light-driven intermolecular electron transfer was observed from a reduced species Ru(bpy)(3)(+), photogenerated via a reductive quenching of the ruthenium photosensitizer by a diethyldithiocarbamate anion, to bioinspired [2Fe2S] model complexes of the iron-only hydrogenase active site. The results indicate that Ru(bpy)(3)(2+) can act as a photoactive functional model of the [4Fe4S] cluster, playing the role of an electron-transfer relay. The photogenerated (FeFe0)-Fe-I species, which is proposed to be a crucial intermediate for proton reduction catalyzed electrochemically by the [2Fe2S] complexes, gives promise in the light-driven dihydrogen evolution using diiron complexes as surrogates of noble platinum catalysts.

sted, utgiver, år, opplag, sider
2007. Vol. 46, nr 10, s. 3813-3815
Emneord [en]
supramolecular systems, homogeneous catalysis, photo-reduction, excited-states, visible-light, evolution, tris(2,2'-bipyridine)ruthenium(ii), mediation, water
Identifikatorer
URN: urn:nbn:se:kth:diva-16605DOI: 10.1021/ic070234kISI: 000246209800009Scopus ID: 2-s2.0-34249701660OAI: oai:DiVA.org:kth-16605DiVA, id: diva2:334647
Merknad
QC 20100525Tilgjengelig fra: 2010-08-05 Laget: 2010-08-05 Sist oppdatert: 2017-12-12bibliografisk kontrollert

Open Access i DiVA

Fulltekst mangler i DiVA

Andre lenker

Forlagets fulltekstScopus

Personposter BETA

Sun, Licheng

Søk i DiVA

Av forfatter/redaktør
Sun, Licheng
Av organisasjonen
I samme tidsskrift
Inorganic Chemistry

Søk utenfor DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric

doi
urn-nbn
Totalt: 23 treff
RefereraExporteraLink to record
Permanent link

Direct link
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf