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Synthesis and structure of a mu-oxo diiron(III) complex with an N-pyridylmethyl-N,N-bis(4-methylbenzimidazol-2-yl)amine ligand and its catalytic property for hydrocarbon oxidation
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2008 (engelsk)Inngår i: Applied organometallic chemistry, ISSN 0268-2605, E-ISSN 1099-0739, Vol. 22, nr 10, s. 573-576Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

A mu-oxo diiron(III) complex [{Fe(pbba)Cl}(2)(mu-O)]Cl-2 (1, pbba = N-pyridylmethyl-N,N-bis(4-methylbenzimidazol-2-yl)amine) bearing multi-imidazolyl motifs was synthesized and characterized by X-ray crystallography to closely mimic the structural features of methane monooxygenase. As shown by its X-ray crystal structure, complex 1 is a centrosymmetric dimer with an Fe-O-Fe angle of 180 degrees, and pseudo-octahedral around each iron(III) center. The catalytic ability of title compound in the oxidation of alkane and alkene is investigated by employing tert-butylhydroperoxide and m-chloroperbenzoic acid as oxidants under mild conditions. The catalytic oxidation results showed that radical intermediate dominates the oxidation process.

sted, utgiver, år, opplag, sider
2008. Vol. 22, nr 10, s. 573-576
Identifikatorer
URN: urn:nbn:se:kth:diva-17866DOI: 10.1002/aoc.1444ISI: 000259780600004Scopus ID: 2-s2.0-53449093027OAI: oai:DiVA.org:kth-17866DiVA, id: diva2:335911
Merknad
QC 20100525Tilgjengelig fra: 2010-08-05 Laget: 2010-08-05 Sist oppdatert: 2017-12-12bibliografisk kontrollert

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