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Development of hexaaluminate catalysts for combustion of gasified biomass in gas turbines
KTH, Tidigare Institutioner                               , Kemiteknik.
2002 (engelsk)Inngår i: Journal of engineering for gas turbines and power, ISSN 0742-4795, E-ISSN 1528-8919, Vol. 124, nr 2, s. 235-238Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

There is an increasing interest in Catalytic combustors fuelled by low-heating value (LHV) gases, with a LHV of 5-7 MJ/Nm(3). This is because catalytic combustion could be advantageous compared to flame combustion with respect to stable combustion of LHV-gases and low conversions of fuel-N (mainly NH3) to NOX. In the present project, funded by the EU Joule Program, catalytic combustion of gasified wood for gas turbine applications is studied. A synthetic gas mixture of H-2, CO, CO2, H2O, CH4, N-2, and NH3, that resembles the output from a fluidized bed gasifier using biomass as raw material, is used. The gas mixture is mixed with air at atmospheric pressure and combusted over wash-coated cordierite monoliths in a bench-scale laboratory quartz-reactor. The objectives of the work described here are twofold. To begin with, improvement of the thermal stability of hexaaluminate washcoats by substitutions of rare earth or transition metal compounds is being studied. Secondly, catalytic combustion of gasified biomass over these washcoats has been studied in a bench-scale unit. In. this on-going project, obtained result show that it is possible to improve the surface area of hexaaluminate compounds up to 17 m(2)/g after careful synthesis and calcination up to 1400degreesC for four hours. The selectivity of NH3-conversion to N-2 is at present at 60 percent, but varies strongly with temperature. Fuel components such as H-2, CO, C2H4, and NH3 ignite at temperatures close to compressor outlet temperatures. This means that a pilot-flame may not be needed for ignition of the fuel. A comparison between a Pd-impregnated lanthanum hexaaluminate and a Mn-substituted lanthanum hexaaluminate showed that the ignition temperature and the NOX-formation varied strongly over the two different catalysts.

sted, utgiver, år, opplag, sider
2002. Vol. 124, nr 2, s. 235-238
Identifikatorer
URN: urn:nbn:se:kth:diva-21508ISI: 000175336200002OAI: oai:DiVA.org:kth-21508DiVA, id: diva2:340206
Merknad
QC 20100525Tilgjengelig fra: 2010-08-10 Laget: 2010-08-10 Sist oppdatert: 2017-12-12bibliografisk kontrollert

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