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Umpolung of the 5-alkyl-2-dimethylamino-1,3-dithiolium-4-thiolate mesoion and its application in the synthesis of some new tetrathiafulvalenes
KTH, Tidigare Institutioner, Kemi.
KTH, Tidigare Institutioner, Kemi.
KTH, Tidigare Institutioner, Kemi.
2004 (engelsk)Inngår i: European Journal of Organic Chemistry, ISSN 1434-193X, E-ISSN 1099-0690, nr 7, s. 1455-1463Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The 5-alkyl-2-dimethylamino-1,3-dithiolium-4-thiolate mesoion could be umpoled with sulfuryl chloride to yield a dicationic electrophile 3 that reacted with various electron-rich aromatic substrates to yield arylthio-substituted 1,3-dithiolium salts 13-25. Two of these compounds have been transformed to the corresponding symmetrical tetrathiafulvalenes 43 and 44, and their cyclovoltammetric behaviour recorded.

sted, utgiver, år, opplag, sider
2004. nr 7, s. 1455-1463
Emneord [en]
umpolung, mesoion, 1, 3-dithiolium ion, tetrathiafulvalene, cyclic voltammetry
HSV kategori
Identifikatorer
URN: urn:nbn:se:kth:diva-45145DOI: 10.1002/ejoc.200300672ISI: 000220655600009Scopus ID: 2-s2.0-4644247321OAI: oai:DiVA.org:kth-45145DiVA, id: diva2:452114
Merknad
QC 20111028Tilgjengelig fra: 2011-10-28 Laget: 2011-10-27 Sist oppdatert: 2017-12-08bibliografisk kontrollert

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