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Utilization of recovered lime-containing materials from pulp and paper industries as slag formers in stainless steel production
KTH, Skolan för industriell teknik och management (ITM), Materialvetenskap.ORCID-id: 0000-0002-9460-6526
2019 (Engelska)Licentiatavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

In recent years, major efforts have been made to develop a more circular economy. The desire to reuse, remanufacture and recycle materials are important for the development towards a sustainable society. An extended lifespan of materials helps to reduce the amount of waste kept in landfills, as well as to reduce the extraction of natural resources. Pulp and paper and steel industries are two of the largest export industrial sectors in Sweden. It is well known that the pulp and paper industries also generates large amounts of organic and inorganic wastes, of which a significant part is kept in landfills. Year by year deposit of wastes in landfills is becoming more difficult to handle and expensive due to stronger regulations and requirements regarding the environment. During Electric Arc Furnace (EAF) and Argon Oxygen Decarburization (AOD) stainless steelmaking operations, burnt lime (primary lime) is charged together with other slag forming materials in the furnace or converter to attain a specific basicity of the slag and to achieve purification from unwanted elements by chemical reactions in the steel.

However, a number of CaO-containing wastes from pulp/paper mills can be used as slag formers in steelmaking processes to replace the currently used burnt natural lime, since the use of this primary lime does not conform with the closing the loop idea that is being prioritized in modern society. This thesis presents results from preliminary experiments for examining the replacement of primary lime with secondary lime from pulp and paper production waste as slag formers in EAF and AOD converters. The obtained results showed a possibility of using up to 30% CaO from secondary lime as a replacement for primary lime in the EAF. Furthermore, the amount of ferrosilicon alloys additions can be decreased by up to 3kg/ton of steel. For the AOD process the use of secondary lime doesn´t have any negative effects on the decarburization process and reduction process. Furthermore, it has similar desulphurization functions as the primary lime. However, the phosphorus content in the metal was slightly increased. Thus, the replacement ratio of secondary lime will be limited by the acceptable phosphorus level in the final steel due to higher phosphorus content in wastes from pulp and paper mills compared to that in primary lime. Moreover, it was revealed during this study that slags from AOD converters can be used as binding agents for briquetting of these secondary lime materials. These results shows that waste/by products from two major industries can be used to make metallurgical briquettes, uniting two major industrial sectors in a circular symbiosis towards a more sustainable future.

Ort, förlag, år, upplaga, sidor
Stockholm: KTH Royal Institute of Technology, 2019. , s. 54
Serie
TRITA-ITM-AVL ; 2019:43
Nationell ämneskategori
Teknik och teknologier
Forskningsämne
Teknisk materialvetenskap
Identifikatorer
URN: urn:nbn:se:kth:diva-264244ISBN: 978-91-7873-396-5 (tryckt)OAI: oai:DiVA.org:kth-264244DiVA, id: diva2:1372664
Presentation
2019-12-18, Sal Sefström, Brinellvägen 23, Stockholm, 10:00 (Engelska)
Opponent
Handledare
Forskningsfinansiär
Vinnova, 2017-01327Tillgänglig från: 2019-11-26 Skapad: 2019-11-25 Senast uppdaterad: 2019-11-26Bibliografiskt granskad
Delarbeten
1. Briquetting of wastes from pulp and paper industries by using AOD converter slag as binders for application in metallurgy
Öppna denna publikation i ny flik eller fönster >>Briquetting of wastes from pulp and paper industries by using AOD converter slag as binders for application in metallurgy
2019 (Engelska)Ingår i: Materials, ISSN 1996-1944, E-ISSN 1996-1944, Vol. 12, nr 18, artikel-id 2888Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

A number of carbon-rich (containing up to 47 wt% C) and lime-rich (containing up to 96 wt% of CaO-compounds) waste products from the pulp and paper industries can be used in iron and steel industry as fuels and slag formers for various metallurgical processes such as blast furnaces (BF), cupola furnaces (CF), argon oxygen decarburization (AOD) converters and electric arc furnaces (EAF). In most cases, these wastes consist of different size powders. In order to facilitate loading, transportation and charging of these powder wastes, briquetting is required. In this study, a pulverized AOD slag was tested as a binder component for briquetting of CaO-containing wastes (such as mesa, lime mud and fly ash) from pulp and paper industries. Moreover, mechanical testing of the possibilities for loading, transportation and unloading operations were done, specifically drop test trials were done for briquettes with different chemical compositions and treatments such as heating and storage. The results showed that an addition of 10-20% of AOD slag as a binder component followed by heat-treatment at 850 °C significantly improved the mechanical properties of the CaO-containing briquettes. An application of these briquettes will significantly reduce the consumption of natural resources (such as nature lime) in the metallurgical processes. Moreover, it can reduce the landfill area of wastes from pulp and paper industries, which is important from an environmental point-of-view.

Ort, förlag, år, upplaga, sidor
MDPI AG, 2019
Nyckelord
Metallurgical briquettes, Recirculation of wastes, Resource saving, Secondary raw materials
Nationell ämneskategori
Materialteknik
Identifikatorer
urn:nbn:se:kth:diva-262500 (URN)10.3390/ma12182888 (DOI)000489126600047 ()2-s2.0-85072564307 (Scopus ID)
Anmärkning

QC 20191017

Tillgänglig från: 2019-10-17 Skapad: 2019-10-17 Senast uppdaterad: 2019-11-25Bibliografiskt granskad

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