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Influence of fibre stretching on the microstructure of self-reinforced poly(ethylene terephthalate) composite
KTH, Skolan för teknikvetenskap (SCI), Farkost och flyg. Scania CV AB, Sweden.ORCID-id: 0000-0001-9909-7620
KTH, Skolan för teknikvetenskap (SCI), Farkost och flyg.ORCID-id: 0000-0002-6616-2964
2016 (Engelska)Ingår i: Journal of reinforced plastics and composites (Print), ISSN 0731-6844, E-ISSN 1530-7964, Vol. 35, nr 21, s. 1634-1641Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Self-reinforced poly(ethylene terephthalate) laminates were prepared from woven fabric by compression moulding. The fabric was stretched to different degrees during heating before hot consolidation to simulate a manufacturing process where the material is stretched through forming. High tenacity poly(ethylene terephthalate) fibres with different degrees of stretching were prepared for a comparison to laminates. Tensile tests were made to characterize mechanical properties, while dynamical mechanical analysis, differential scanning calorimetry, FTIR spectroscopy and X-ray diffraction analysis were employed to study microstructural changes caused by the stretching. Tensile tests show that 13% stretching of the fabric increases the laminate tensile stiffness by 34%. However, same degree of stretching for pure fibres increases the fibre tensile stiffness by 111%. Crystallinity and molecular conformations are not influenced by stretching while shrinkage upon heating increases with degree of stretching. Shrinkage is known to be related to disorientation of non-crystalline regions whereof the conclusion from this study is that the increased tensile properties are due to orientation of the non-crystalline regions of the fibre.

Ort, förlag, år, upplaga, sidor
2016. Vol. 35, nr 21, s. 1634-1641
Nyckelord [en]
Self-reinforced polymer composite, poly(ethylene terephthalate), microstructural analysis, mechanical properties
Nationell ämneskategori
Polymerteknologi
Identifikatorer
URN: urn:nbn:se:kth:diva-196978DOI: 10.1177/0731684416662328ISI: 000386959000003Scopus ID: 2-s2.0-84994092870OAI: oai:DiVA.org:kth-196978DiVA, id: diva2:1055970
Anmärkning

QC 20161213

Tillgänglig från: 2016-12-13 Skapad: 2016-11-28 Senast uppdaterad: 2017-12-14Bibliografiskt granskad
Ingår i avhandling
1. Processing of self-reinforced poly(ethylene terephthalate) composites for automotive applications
Öppna denna publikation i ny flik eller fönster >>Processing of self-reinforced poly(ethylene terephthalate) composites for automotive applications
2017 (Engelska)Doktorsavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

The vehicles of the future must have less negative environmental impact during their use phase than the vehicles of today in order to avoid major climate change on earth. Consequently electric vehicles are currently under development with the purpose of reducing CO2 emissions when the vehicle is

driven. There are also efforts put in to reducing the weight of vehicles in order to reduce the demand for energy to drive them. One important aspect of weight reduction is that new materials and technologies are developed. Plastic materials have low a density and can therefore be used to reduce the weight of vehicle components and with composite materials there is further potential for weight reduction. Self-reinforced thermoplastic composite materials are materials in which both reinforcement and matrix are thermoplastic materials and thanks to their low density and relatively good mechanical properties, these materials may be used for weight reduction of vehicle components.

 

The aim of this thesis is to study selected process parameters for component manufacturing with self-reinforced poly(ethylene terephthalate) (SrPET) in order to increase knowledge and thereby advance the field of self-reinforced PET composites. This thesis shows that stretching the material in the manufacturing process increases the mechanical performance of the material due to increased orientation of the amorphous phase in the PET reinforcement. However, stretching introduces stresses in the material that give rise to negative shape distortions in the formed component. The degree of stretching during forming must therefore be controlled in order to achieve a robust serial production. The concept of a SrPET component over-moulded for integration of stiffeners and attachments has been evaluated in a life-cycle-assessment. This evaluation shows that the component weight can be reduced compared to technology currently in use and thereby contribute to increased sustainability of transport.

Ort, förlag, år, upplaga, sidor
Stockholm: KTH Royal Institute of Technology, 2017
Serie
TRITA-AVE, ISSN 1651-7660 ; 2017:94
Nationell ämneskategori
Kompositmaterial och -teknik
Forskningsämne
Farkostteknik
Identifikatorer
urn:nbn:se:kth:diva-219926 (URN)978-91-7729-651-5 (ISBN)
Disputation
2018-01-26, Kollegiesalen, Brinellvägen 8, Stockholm, 09:00 (Engelska)
Opponent
Handledare
Anmärkning

QC 20171215

Tillgänglig från: 2017-12-15 Skapad: 2017-12-14 Senast uppdaterad: 2017-12-15Bibliografiskt granskad

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