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Light-Induced Interfacial Dynamics Dramatically Improve the Photocurrent in Dye-Sensitized Solar Cells: An Electrolyte Effect
KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.ORCID-id: 0000-0001-5115-4593
Uppsala Univ, Angstrom Lab, Dept Chem, Box 523, SE-75120 Uppsala, Sweden..
Flinders Univ S Australia, Flinders Ctr NanoScale Sci & Technol CNST, Adelaide, SA 5042, Australia..
Dyenamo AB, Greenhouse Labs, Tekn Ringen 38A, SE-11428 Stockholm, Sweden..
Visa övriga samt affilieringar
2018 (Engelska)Ingår i: ACS Applied Materials and Interfaces, ISSN 1944-8244, E-ISSN 1944-8252, Vol. 10, nr 31, s. 26241-26247Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

A significant increase in the photocurrent generation during light soaking for solar cells sensitized by the triphenylamine-based D-pi-A organic dyes (PD2 and LEG1) and mediated by cobalt bipyridine redox complexes has been observed and investigated. The crucial role of the electrolyte has been identified in the performance improvement. Control experiments based on a pretreatment strategy reveals TBP as the origin. The increase in the current and IPCE has been interpreted by the interfacial charge-transfer kinetics studies. A slow component in the injection kinetics was exposed for this system. This change explains the increase in the electron lifetime and collection efficiency. Photoelectron spectroscopic measurements show energy shifts at the dye/TiO2 interface, leading us to formulate a hypothesis with respect to an electrolyte induced dye reorganization at the surface.

Ort, förlag, år, upplaga, sidor
AMER CHEMICAL SOC , 2018. Vol. 10, nr 31, s. 26241-26247
Nyckelord [en]
dye-sensitized solar cells, electrolyte, interface, dynamics, light soaking
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URN: urn:nbn:se:kth:diva-234184DOI: 10.1021/acsami.8b06897ISI: 000441477800045PubMedID: 29996051Scopus ID: 2-s2.0-85049917640OAI: oai:DiVA.org:kth-234184DiVA, id: diva2:1252927
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QC 20181003

Tillgänglig från: 2018-10-03 Skapad: 2018-10-03 Senast uppdaterad: 2019-12-09Bibliografiskt granskad

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Gao, JiajiaSafdari, MajidGardner, James M.Kloo, Lars

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Gao, JiajiaLeandri, ValentinaSafdari, MajidGardner, James M.Kloo, Lars
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