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Characterization of Two Novel Bio-based Materials from Pulping Process Side Streams: Ecohelix and CleanFlow Black Lignin
KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Fiber- och polymerteknologi.
KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Fiber- och polymerteknologi. Ecohelix AB, Teknikringen 38, SE-10044 Stockholm, Sweden..
KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Fiber- och polymerteknologi.ORCID-id: 0000-0001-8817-2031
2018 (Engelska)Ingår i: BioResources, ISSN 1930-2126, E-ISSN 1930-2126, Vol. 13, nr 4, s. 7606-7627Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

The characteristics of two novel types of technical lignin, namely Ecohelix (EH) and CleanFlow black lignin (CFBL), isolated from two different pulping process side streams, were analyzed. EH and CFBL were analyzed in terms of general composition, chemical functionalities, molar mass distribution, and thermal stability. For comparison, two relevant types of commercially available lignosulfonate and kraft lignin were used. The results showed that EH contains a large amount of sulfonated lignin, together with carbohydrates and ash. As such, it can be considered a lignin-carbohydrate hybrid molecule. CFBL was found to contain 91.5% Klason lignin and the lowest amount of carbohydrates (0.3%). EH showed the highest content of aliphatic OH groups (5.44 mmol/g) and CFBL a high content of phenols (4.73 mmol/g). EH had a molecular weight of 31.4 kDa and a sufficient thermal stability. CFBL had the lowest molecular weight (M-w = 2.0 kDa) and thermal stability of all kraft lignins analyzed in this study. These properties highlighted that EH is a suitable building block for material development and that CFBL is a promising material for the production of biofuel and biochemicals.

Ort, förlag, år, upplaga, sidor
NORTH CAROLINA STATE UNIV DEPT WOOD & PAPER SCI , 2018. Vol. 13, nr 4, s. 7606-7627
Nyckelord [en]
Lignin characterization, Lignin-carbohydrate complexes, Laccase, Ultrafiltered lignin, Kraft lignin, Lignosulfonate, RUITER GA, 1992, ANALYTICAL BIOCHEMISTRY, V207, P176 Kendry P, 2002, BIORESOURCE TECHNOLOGY, V83, P55 woko M, 2005, BIOMACROMOLECULES, V6, P3467
Nationell ämneskategori
Kemi
Identifikatorer
URN: urn:nbn:se:kth:diva-241237DOI: 10.15376/biores.13.4.7606-7627ISI: 000454215100033OAI: oai:DiVA.org:kth-241237DiVA, id: diva2:1279502
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QC 20190116

Tillgänglig från: 2019-01-16 Skapad: 2019-01-16 Senast uppdaterad: 2019-03-18Bibliografiskt granskad

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Abbadessa, AnnaOinonen, PetriHenriksson, Gunnar

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