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The role of Sn on the long-term atmospheric corrosion of binary Cu-Sn bronze alloys in architecture
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Surface and Corrosion Science.ORCID iD: 0000-0002-2510-7766
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Surface and Corrosion Science.ORCID iD: 0000-0002-2123-2201
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2019 (English)In: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 149, p. 54-67Article in journal (Refereed) Published
Abstract [en]

The role of Sn on the atmospheric corrosion performance of binary Cu-Sn bronze alloys (4–6 wt.% Sn) compared with Cu metal used in outdoor architecture is elucidated in terms of microstructure, native surface oxide composition, patina evolution, corrosion rates, appearance and metal release. Results are presented for non-exposed surfaces and surfaces exposed at different urban and marine sites in Europe up to 5 years and based on multi-analytical findings from microscopic, spectroscopic, electrochemical and chemical investigations. Alloying influenced the corrosion, aesthetic appearance and patina evolution, differently for urban and marine sites, whereas no effects were observed on the release pattern.

Place, publisher, year, edition, pages
Elsevier, 2019. Vol. 149, p. 54-67
Keywords [en]
Aesthetic appearance, Atmospheric corrosion, Bronze, Metal release, Patina
National Category
Metallurgy and Metallic Materials
Identifiers
URN: urn:nbn:se:kth:diva-246467DOI: 10.1016/j.corsci.2019.01.002ISI: 000459839700006Scopus ID: 2-s2.0-85059532533OAI: oai:DiVA.org:kth-246467DiVA, id: diva2:1299755
Note

QC 20190328

Available from: 2019-03-28 Created: 2019-03-28 Last updated: 2019-03-28Bibliographically approved

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Chang, TingruHerting, GunillaLeygraf, ChristopherOdnevall Wallinder, Inger

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