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The role of Sn on the long-term atmospheric corrosion of binary Cu-Sn bronze alloys in architecture
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Surface and Corrosion Science. Univ Sci & Technol Beijing, Natl Ctr Mat Serv Safety, Beijing 100083, Peoples R China.ORCID iD: 0000-0002-2510-7766
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Surface and Corrosion Science.ORCID iD: 0000-0002-2123-2201
Politecn Milan, Dept Chem Mat & Chem Engn Giulio Natta, Via Mancinelli 7, I-0131 Milan, Italy..
LABCYP, Dept Mat Sci & Met Engn & Inorgan Chem, Sch Engn, Ave Univ Cadiz 10, Cadiz 11519, Spain..
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2019 (English)In: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 149, p. 54-67Article in journal (Refereed) Published
Abstract [en]

The role of Sn on the atmospheric corrosion performance of binary Cu-Sn bronze alloys (4-6 wt.% Sn) compared with Cu metal used in outdoor architecture is elucidated in terms of microstructure, native surface oxide composition, patina evolution, corrosion rates, appearance and metal release. Results are presented for non-exposed surfaces and surfaces exposed at different urban and marine sites in Europe up to 5 years and based on multi-analytical findings from microscopic, spectroscopic, electrochemical and chemical investigations. Alloying influenced the corrosion, aesthetic appearance and patina evolution, differently for urban and marine sites, whereas no effects were observed on the release pattern.

Place, publisher, year, edition, pages
PERGAMON-ELSEVIER SCIENCE LTD , 2019. Vol. 149, p. 54-67
Keywords [en]
Bronze, Atmospheric corrosion, Patina, Metal release, Aesthetic appearance, SLOUIS C, 1993, ELECTROCHIMICA ACTA, V38, P2781 yer H.E., 1985, yer J.H., 1992, Bronze Corrosion: Rates and Chemical Processes, the Conservation of Bronze Sculpture in the Outdoor Environment: a Dialogue Among Conservators, Curators, Environmental Scientists, and Corrosion Engineers, P103 hweizer F., 1994, Bronze Objects From Lake Sites: From Patina to Biography, Ancient and Historic Metals: Conservation and Scientific Research, P33 nonymous], ISO 9226, armaraj N, 2006, SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, V64, P136 W., 2001, Water Air Soil Pollut. Focus, V1, P67 ott DA, 2000, STUDIES IN CONSERVATION, V45, P39 otkova D., 1996, Proc. of Art' 96
National Category
Corrosion Engineering
Identifiers
URN: urn:nbn:se:kth:diva-246227DOI: 10.1016/j.corsci.2019.01.002ISI: 000459839700006Scopus ID: 2-s2.0-85059532533OAI: oai:DiVA.org:kth-246227DiVA, id: diva2:1302330
Note

QC 20190404

Available from: 2019-04-04 Created: 2019-04-04 Last updated: 2019-04-04Bibliographically approved

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Chang, TingruHerting, GunillaLeygraf, ChristopherOdnevall Wallinder, Inger

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