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Novel definition of the synergistic effect between carbon nanotubes and carbon black for electrical conductivity
Friedrich Alexander Univ Erlangen Nuremberg, Inst Polymer Mat, Martensstr 7, D-91058 Erlangen, Germany.;BPI, Key Lab Adv Fiber Technol, Dr Mack Str 77, D-90762 Furth, Germany..
KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Fiber- och polymerteknologi.
Friedrich Alexander Univ Erlangen Nuremberg, Inst Polymer Mat, Martensstr 7, D-91058 Erlangen, Germany.;BPI, Key Lab Adv Fiber Technol, Dr Mack Str 77, D-90762 Furth, Germany..
2019 (engelsk)Inngår i: Nanotechnology, ISSN 0957-4484, E-ISSN 1361-6528, Vol. 30, nr 24, artikkel-id 245703Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Anisotropic ternary composites comprising poly(methy-methacrylate) (PMMA), carbon black (CB), and carbon nanotubes (CNTs) were extruded using a capillary rheometer and the electrical conductivities of the composites were measured and presented in a detailed contour plot covering a large range of filler fractions (up to 30 vol% CNTs, 20 vol% CB). A recent generic conductivity model for ternary composites was successfully validated using the conductivity measurements. When analyzing the conductivity measurements using four traditional definitions of 'synergy' between two conductive fillers, no clear synergetic effect was observed between CB and CNT. Also, when all the conductivity data for ternary CNT/CB composites from the existing literature was carefully gathered and analyzed, the number of confirmed occurrences of strong and convincing CNT/CB synergies was surprisingly low. Finally, a novel definition of synergy based on the physical aspect, in particular, its maximum, the 'synergasm', was defined in order to obtain a more precise instrument for revealing regions of potential synergy.

sted, utgiver, år, opplag, sider
Institute of Physics (IOP), 2019. Vol. 30, nr 24, artikkel-id 245703
Emneord [en]
carbon nanotubes, carbon black, electrical properties, synergistic effect
HSV kategori
Identifikatorer
URN: urn:nbn:se:kth:diva-249840DOI: 10.1088/1361-6528/ab0becISI: 000462890900001PubMedID: 30822767Scopus ID: 2-s2.0-85064144640OAI: oai:DiVA.org:kth-249840DiVA, id: diva2:1313035
Merknad

QC 20190502

Tilgjengelig fra: 2019-05-02 Laget: 2019-05-02 Sist oppdatert: 2019-05-02bibliografisk kontrollert

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