Endre søk
RefereraExporteraLink to record
Permanent link

Direct link
Referera
Referensformat
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf
Mild and Rapid Aniline/HBF4 center dot DEE-Catalysed Formation of Sulfinyl Imines
KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Kemi, Organisk kemi.
KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Kemi, Organisk kemi.ORCID-id: 0000-0001-6782-6622
2019 (engelsk)Inngår i: ChemistrySelect, ISSN 2365-6549, Vol. 4, nr 25, s. 7431-7436Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The combination of anline and tetrafluoroboric acid diethyl etherate (2.5 mol% and 5 mol%, respectively) significantly accelerates the formation of sulfinyl imines in dichloromethane and isopropylacetate at room temperature compared to previous procedures. A DFT and NMR spectroscopic study shows that the anilinium tetrafluoroborate complex is solvated by sulfinamide molecules in the initial state and that the rate-limiting step of the reaction is the addition of the sulfinamide molecule to the protonated aniline-based imine. In addition, the catalytic system was also utilised in a one-pot, two step reaction, where the in situ formed sulfinyl imine was arylated in a rhodium catalysed reaction with high diastereoselectivity.

sted, utgiver, år, opplag, sider
Wiley-VCH Verlagsgesellschaft, 2019. Vol. 4, nr 25, s. 7431-7436
Emneord [en]
Sulfinylimines, Organic synthesis, Organocatalysis, DFT, NMR
HSV kategori
Identifikatorer
URN: urn:nbn:se:kth:diva-255378DOI: 10.1002/slct.201901218ISI: 000474296800005Scopus ID: 2-s2.0-85068481356OAI: oai:DiVA.org:kth-255378DiVA, id: diva2:1339595
Merknad

QC 20190730

Tilgjengelig fra: 2019-07-30 Laget: 2019-07-30 Sist oppdatert: 2019-07-30bibliografisk kontrollert

Open Access i DiVA

Fulltekst mangler i DiVA

Andre lenker

Forlagets fulltekstScopus

Personposter BETA

Dinér, Peter

Søk i DiVA

Av forfatter/redaktør
Blomkvist, BjörnDinér, Peter
Av organisasjonen

Søk utenfor DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric

doi
urn-nbn
Totalt: 99 treff
RefereraExporteraLink to record
Permanent link

Direct link
Referera
Referensformat
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf