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Making an ultralow platinum content bimetallic catalyst on carbon fibres for electro-oxidation of ammonia in wastewater
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology. Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Göteborg, 41296, Sweden.
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.ORCID iD: 0000-0002-0236-5420
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering.ORCID iD: 0000-0003-2170-0076
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2019 (English)In: Sustainable Energy and Fuels, ISSN 2398-4902, Vol. 3, no 8, p. 2111-2124Article in journal (Refereed) Published
Abstract [en]

Electrocatalysis of wastewater containing ammonia is a promising alternative to chemical and biological water purification for several reasons, one being that energy-rich hydrogen gas is generated as a by-product while the reaction can be strictly controlled to meet demands. An objective has been to reduce the loading of expensive platinum (Pt) in the catalyst electrodes, and to reduce the poisoning of the metal surface during the electrolysis. Herein, the co-deposition of a copper-platinum (Cu-Pt) bimetallic alloy onto carbon filaments, stripped from their polymeric coating, is shown to give an electrocatalytic performance superior to that of pure Pt at a content of less than 3 wt% Pt. The key to the enhanced performance was to take advantage of micrometer-sized carbon filaments to distribute a very large bimetallic alloy surface uniformly over the filaments. The Cu-Pt-alloy-coated filaments also suffer less electrode poisoning than pure Pt, and are bonded more strongly to the carbon fibre due to better mechanical interlocking between the bimetallic alloy and the carbon filaments. High-resolution electron microscopy studies combined with a tuned electro-deposition process made it possible to tailor the catalyst micro/nano morphology to reach a uniform coverage, surrounding the entire carbon filaments. The results are promising steps towards large-scale wastewater treatment, combined with clean energy production from regenerated hydrogen.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2019. Vol. 3, no 8, p. 2111-2124
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Other Chemical Engineering
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URN: urn:nbn:se:kth:diva-255760DOI: 10.1039/c9se00161aISI: 000476912900020Scopus ID: 2-s2.0-85069762947OAI: oai:DiVA.org:kth-255760DiVA, id: diva2:1341631
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QC 20190809

Available from: 2019-08-09 Created: 2019-08-09 Last updated: 2019-08-09Bibliographically approved

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Andersson, Richard L.Ström, Valter

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