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Towards implementing hierarchical porous zeolitic imidazolate frameworks in dye-sensitized solar cells
Stockholm Univ, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden.;Assiut Univ, Dept Chem, Adv Multifunct Mat Lab, Assiut 71515, Egypt..ORCID-id: 0000-0002-3106-8302
Uppsala Univ, Dept Chem, Angstrom Labs, POB 523, S-75120 Uppsala, Sweden..
KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Kemi, Tillämpad fysikalisk kemi.ORCID-id: 0000-0001-8084-1181
Stockholm Univ, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden..
Vise andre og tillknytning
2019 (engelsk)Inngår i: Royal Society Open Science, E-ISSN 2054-5703, Vol. 6, nr 7, artikkel-id 190723Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

A one-pot method for encapsulation of dye, which can be applied for dye-sensitized solar cells (DSSCs), and synthesis of hierarchical porous zeolitic imidazolate frameworks (ZIF-8), is reported. The size of the encapsulated dye tunes the mesoporosity and surface area of ZIF-8. The mesopore size, Langmuir surface area and pore volume are 15 nm, 960-1500 m(2). g(-1) and 0.36-0.61 cm(3). g(-1), respectively. After encapsulation into ZIF-8, the dyes show longer emission lifetimes (greater than 4-8-fold) as compared to the corresponding non-encapsulated dyes, due to suppression of aggregation, and torsional motions.

sted, utgiver, år, opplag, sider
Royal Society Publishing , 2019. Vol. 6, nr 7, artikkel-id 190723
Emneord [en]
zeolitic imidazolate frameworks, hierarchical Porous ZIF-8, dye encapsulation, dye-sensitized solar cells, photophysical properties, emission lifetime
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Identifikatorer
URN: urn:nbn:se:kth:diva-257464DOI: 10.1098/rsos.190723ISI: 000479146300079PubMedID: 31417762Scopus ID: 2-s2.0-85070743581OAI: oai:DiVA.org:kth-257464DiVA, id: diva2:1347097
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QC 20190830

Tilgjengelig fra: 2019-08-30 Laget: 2019-08-30 Sist oppdatert: 2019-08-30bibliografisk kontrollert

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