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Monodisperse highly ordered chitosan/cellulose nanocomposite foams
Univ Stuttgart, Inst Phys Chem, Pfaffenwaldring 55, D-70569 Stuttgart, Germany.;Inst Charles Sadron UPR22 CNRS, 23 Rue Loess, F-67034 Strasbourg 2, France..
KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Fiber- och polymerteknologi, Biokompositer. KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Centra, Wallenberg Wood Science Center.ORCID-id: 0000-0001-8547-9046
Univ Stuttgart, Inst Phys Chem, Pfaffenwaldring 55, D-70569 Stuttgart, Germany..
KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Fiber- och polymerteknologi, Biokompositer. KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Centra, Wallenberg Wood Science Center.ORCID-id: 0000-0001-5818-2378
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2019 (Engelska)Ingår i: Composites. Part A, Applied science and manufacturing, ISSN 1359-835X, E-ISSN 1878-5840, Vol. 125, artikel-id UNSP 105516Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

In solid foams, most physical properties are determined by the pore size and shape distributions and the organisation of the pores. For this reason, it is important to control the structure of porous materials. We recently tackled this issue with the help of microfluidic-aided foam templating, which allowed us to generate mono-disperse and highly ordered chitosan foams. However, the properties of foams also depend on the properties of the pore wall constituents. In case of chitosan-based foams, the foams have poor absolute mechanical properties, simply due to the fact that the solubility of chitosan in water is very low, so that the relative density of the freeze-dried foams becomes very small. Drawing inspiration from the field of nanocomposites, we incorporated cellulose nanofibres into the foamed chitosan solutions, with a view to strengthening the pore walls in the foam and thus the mechanical properties of the final foam. We report here how the cellulose nanofibres affect the structure of both the liquid foam template and the solid foam. The resulting nanocomposite foams have improved mechanical properties, which, however, are not proportional to the amount of cellulose nanofibres in the composites. One reason for this observation is the disturbance of the porous structure of the solid foams by the cellulose nanofibres.

Ort, förlag, år, upplaga, sidor
ELSEVIER SCI LTD , 2019. Vol. 125, artikel-id UNSP 105516
Nyckelord [en]
Cellulose, Foams, Nanocomposites, Mechanical testing
Nationell ämneskategori
Polymerkemi
Forskningsämne
Fiber- och polymervetenskap
Identifikatorer
URN: urn:nbn:se:kth:diva-261001DOI: 10.1016/j.compositesa.2019.105516ISI: 000484878200005Scopus ID: 2-s2.0-85068544162OAI: oai:DiVA.org:kth-261001DiVA, id: diva2:1357851
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QC 20191004

Tillgänglig från: 2019-10-04 Skapad: 2019-10-04 Senast uppdaterad: 2019-11-26Bibliografiskt granskad

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Medina, LilianBerglund, Lars

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Medina, LilianBerglund, Lars
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BiokompositerWallenberg Wood Science Center
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Composites. Part A, Applied science and manufacturing
Polymerkemi

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