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Synergetic Effect of Water-Soluble PEG-Based Macromonomers and Cellulose Nanocrystals for the Stabilization of PMMA Latexes by Surfactant-Free Emulsion Polymerization
Univ Lyon, Univ Claude Bernard Lyon 1, Chem Catalysis Polymers & Proc C2P2, CPE Lyon,CNRS,UMR 5265, F-69616 Villeurbanne, France..
Univ Lyon, Univ Claude Bernard Lyon 1, Chem Catalysis Polymers & Proc C2P2, CPE Lyon,CNRS,UMR 5265, F-69616 Villeurbanne, France..
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Centres, Wallenberg Wood Science Center. KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Coating Technology.ORCID iD: 0000-0002-9572-6888
Univ Lyon, Univ Claude Bernard Lyon 1, Chem Catalysis Polymers & Proc C2P2, CPE Lyon,CNRS,UMR 5265, F-69616 Villeurbanne, France..
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2020 (English)In: Biomacromolecules, ISSN 1525-7797, E-ISSN 1526-4602, Vol. 21, no 11, p. 4479-4491Article in journal (Refereed) Published
Abstract [en]

The combination of cellulose nanocrystals (CNCs ) and poly(ethylene glycol) methyl ether methacrylate (PEGMA) was evaluated to synthesize stable latexes by surfactant-free emulsion polymerization of methyl methacrylate (MMA). Cellulose-particle interaction was provided due to the dual role of PEGMA, acting as water-soluble comonomer with MMA under emulsion polymerization conditions and able to interact with CNCs, recovered from sulfuric acid hydrolysis (H2SO4-CNCs). After preliminary experiments designed to validate the affini ty between CNCs and PEG-stabilized PMMA particles obtained by MMA/PEGMA emulsion copolymerization, the effect of the PEGMA content and molar mass and also of the content of CNCs on the kinetics of the polymerization and the stability of the latexes were investigated. The use of PEGMA 300 (M-n = 300 g mol(-1),2-10 wt %) allowed the formation of a stable latex, however, with a broad particle size distribution and the presence of both small (ca. 25-50 nm) and large (ca. 425-650 nm) particles (at 10 wt %, D-n = 278 nm and D-w/D-n = 1.34). Increasing the molar mass of PEGMA (PEGMA(950) or PEGMA(2080)) significantly increased the fraction of small partides. This was explained by the nucleation and growth of small polymer particles adsorbed at the CNCs' surface, resulting in a particular organization where the CNCs were covered by several polymer particles. The influence of the initial amount of CNCs in these systems was finally evidenced, the polymerization being faster as the content of CNCs increased, but only the latexes prepared with 2 and 5 wt % of CNCs were stable.

Place, publisher, year, edition, pages
American Chemical Society (ACS) , 2020. Vol. 21, no 11, p. 4479-4491
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-289268DOI: 10.1021/acs.biomac.0c00439ISI: 000592221000008PubMedID: 32551526Scopus ID: 2-s2.0-85095861524OAI: oai:DiVA.org:kth-289268DiVA, id: diva2:1522981
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QC 20210127

Available from: 2021-01-27 Created: 2021-01-27 Last updated: 2022-06-25Bibliographically approved

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Engström, JoakimCarlmark, AnnaMalmström, Eva

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