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A high-temperature thermal stability and optical property study of inorganic coatings on ceramic particles for potential thermal energy storage applications
KTH, School of Industrial Engineering and Management (ITM), Energy Technology, Heat and Power Technology.ORCID iD: 0000-0003-4932-7103
KTH, School of Industrial Engineering and Management (ITM), Energy Technology, Heat and Power Technology.ORCID iD: 0000-0003-4134-3520
KTH, School of Industrial Engineering and Management (ITM), Energy Technology, Heat and Power Technology.ORCID iD: 0000-0001-7193-5303
2022 (English)In: Solar Energy Materials and Solar Cells, ISSN 0927-0248, E-ISSN 1879-3398, Vol. 239, article id 111679Article in journal (Refereed) Published
Abstract [en]

Ceramic-based packed bed solutions are becoming more common in the energy fields as both thermal energy storage and heat exchanger. Such solutions are usually designed for the working temperature ranges above600 ◦C, thus thermal radiation becomes significant and even acts as the dominant heat transfer mechanism. Therefore, applying high-temperature coatings with different thermal properties could be an efficient way in enhancing the performance of these applications. In this work, the high-temperature long residency and cyclic thermal stability of six inorganic coatings applied on a ceramic substrate are investigated. Both qualitative and quantitative assessments are performed. The results show that HIE-Coat 840MX and Pyropaint 634 ZO exhibit excellent thermal stability performance both at high-temperature testing (1000 ◦C) and under thermal cycle testing (400 ◦C–800 ◦C). TiO2 based coatings could be a viable solution if the powder is pre-treated to avoid polymorph transition during the operation. Stainless steel 304 powder-based coating could also be a possible solution, since the adhesive curbs the oxidation and hinders the coating from deterioration. Contrarily, Pyromark2500 and MgO-based coating show different degradation problems that limit their exploitation in high-temperature applications undergoing thermal cycles. The investigated coatings show a wide range of thermal emissivity (between 0.6 and 0.9), with stable or decreasing trends with temperature. This enables a potential20% change of the effective thermal conductivity for the packing structure. This work is a stepping-stone towards further detailed experimental studies on the influence of coatings on various packed bed thermal storage systems, and thus offer a new option in improving the performances of the energy equipment with packed bed systems.

Place, publisher, year, edition, pages
Elsevier BV , 2022. Vol. 239, article id 111679
Keywords [en]
Packed bed thermal energy storage, Thermal emissivity, Inorganic coating, Effective thermal conductivity, Thermal stability
National Category
Energy Engineering
Research subject
Energy Technology
Identifiers
URN: urn:nbn:se:kth:diva-309657DOI: 10.1016/j.solmat.2022.111679ISI: 000781853600001Scopus ID: 2-s2.0-85125538395OAI: oai:DiVA.org:kth-309657DiVA, id: diva2:1642959
Funder
Swedish Energy Agency, P43284-1Swedish Energy Agency, P46287-1
Note

QC 20220502

Available from: 2022-03-08 Created: 2022-03-08 Last updated: 2022-06-25Bibliographically approved
In thesis
1. Renewable Heat on Demand: High-temperature thermal energy storage: a comprehensive study from material investigation to system analysis via innovative component design
Open this publication in new window or tab >>Renewable Heat on Demand: High-temperature thermal energy storage: a comprehensive study from material investigation to system analysis via innovative component design
2022 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

High-temperature thermal energy storage could enable widespread exploitation of renewable energy sources, providing the required energy flexibility. Technology and component development is needed to enhance the storage thermo-dynamic performance, and identify key design features. Similarly, system-level integration studies are required to fully understand the techno-economic potential of high-temperature thermal energy storage as integrated into different energy systems. This research work focuses on the development of an innovative packed bed high-temperature thermal energy storage and a multi-level investigation of the potential of this technology. The integration and techno-economic performance of a packed bed thermal energy storage have been studied focusing primarily on its application within concentrating solar power plants. Numerical studies and experimental tests have been conducted assessing the suitability of various coatings to optimize the heat transfer in high-temperature packed beds. A comprehensive design of an innovative packed bed thermal energy storage prototype and its experimental evaluation have been presented. Adapted numerical models have also been validated based on the experimental results, providing the ground for further technology development.The outcomes of this research work show that packed bed thermal energy storage could be a key component in air-driven concentrating solar powerplants, granting high capacity factor while limiting the capital costs. The designed radial flow packed bed storage showed thermal efficiency of about72 % and extremely low-pressure drops. Thermocline degradation control strategies and proper packing have been highlighted as key aspects to target for further development. This research also highlights that accurate boundary conditions should be accounted for when designing packed bed thermal energy storage. Innovative figures of merit, such as the Levelized Cost ofStorage, should be included in the design process. The outcomes of this work show also that coatings could be exploited to modify the particle surface properties while optimizing the heat transfer within packed bed units. In particular, high emissivity coatings could enhance the effective thermal conductivity, while coatings with low thermal emissivity could be exploited as a form of passive thermocline control. Finally, this work testifies that high temperature packed bed could represent a techno-economically valuable energy storage solution. Optimized packed bed designs and their system integration could enable higher renewable penetration, as well as the recovery of a large amount of waste heat from the hard-to-abate and energy-intensive industrial sector.

Abstract [sv]

Lagring av termisk energi vid hög temperatur kan möjliggöra en omfattande exploatering av förnybara energikällor, vilket ger den erforderliga energiflexibiliteten för ett klimatneutralt samhälle. Teknik och komponentutveckling behövs för att maximera den termodynamiska prestandan för lagring och för att identifiera viktiga designparametrar. På samma sätt krävs integrationsstudier på systemnivå för att fullt ut förstå den tekno-ekonomiska potentialen vid lagring av termisk energi vid hög temperatur.

Detta forskningsarbete fokuserar på utveckling och provning av en innovativ lagringsteknologi av värmeenergi i packade bäddar och en undersökning av potentialen för denna teknologi. Integrationen och den teknikekonomiska prestandan för en högtempererad termisk bädd har studerats i samband med anläggningar för koncentrerad solkraft. Numeriska studier och experimentella tester har genomförts för att bedöma prestandan av olika partikelytskikt i bäddmaterialet och för att optimera värmeöverföringen i termiska bäddar med hög temperatur. Den omfattande designen av en innovativ prototyp för lagring av högtemperatur-värme med packade bäddar och dess experimentella utvärdering presenteras. Anpassade numeriska modeller har också validerats baserat på experimentella resultat, vilket ger grunden för ytterligare teknikutveckling.

Resultaten av detta forskningsarbete visar att lagring av termisk energi för packade bäddar kan vara en nyckelteknologi i luftdrivna koncentrerade solkraftverk, då dessa levererar en hög kapacitetsfaktor samtidigt som kapitalkostnaderna begränsas. Den i detta arbete utvecklade innovativa radialflödesbädden visade en effektivitet på cirka 72 % vid extremt låga tryckfall. Termokline-kontroll och en noggrann och välfördelad packning har lyfts fram som viktiga aspekter att rikta in vidare utveckling på. Exakta flödesgränsskiktsförhållanden bör också beaktas vid konstruktion av termisk energilagring i packade bäddar. Nya nyckeltal som föreslås i detta arbete, till exempel den nivellerade lagringskostnaden, bör ingå i designprocessen eftersom de visas vara mindre beroende av specifika driftförhållanden. Partikelytskikt med hög emissivitet kan utnyttjas för att förbättra den effektiva värmeledningsförmågan. Medan ytskikt med minskande värmeemissivitet kan utnyttjas som en form av passiv termokline-kontroll.

Slutsatsen av detta arbete är att högtempererade packade bäddar skulle kunna representera en tekniskt och ekonomiskt värdefull energilagringslösning. Optimerade packade bädd-designer och deras systemintegration skulle kunna möjliggöra högre penetration av förnybar energi, såväl som återvinning av en stor mängd spillvärme från den energiintensiva industrisektorn.

 

Nyckelord

Värmeenergilagring, packad bädd, teknikekonomisk analys, komponentdesign, experimentell utvärdering.

Place, publisher, year, edition, pages
Stockholm: KTH Royal Institute of Technology, 2022. p. 295
Series
TRITA-ITM-AVL ; 2022:4
National Category
Energy Engineering
Research subject
Energy Technology
Identifiers
urn:nbn:se:kth:diva-309660 (URN)978-91-8040-169-2 (ISBN)
Public defence
2022-04-01, M3 / https://kth-se.zoom.us/j/68531114425, Brinellvägen 64, Stockholm, 13:00 (English)
Opponent
Supervisors
Funder
Swedish Energy Agency, P43284-1
Available from: 2022-03-17 Created: 2022-03-08 Last updated: 2022-09-13Bibliographically approved

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Trevisan, SilviaWang, WujunLaumert, Björn

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