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Design of Highly Oleophobic Cellulose Surfaces from Structured Silicon Templates
KTH, Skolan för kemivetenskap (CHE), Fiber- och polymerteknologi, Fiberteknologi.
KTH, Skolan för kemivetenskap (CHE), Fiber- och polymerteknologi.ORCID-id: 0000-0001-8622-0386
KTH, Skolan för informations- och kommunikationsteknik (ICT), Mikroelektronik och tillämpad fysik, MAP.
2009 (Engelska)Ingår i: Applied Materials and Interfaces, ISSN 1944-8244, Vol. 1, nr 11, s. 2443-2452Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Structured silicon surfaces, possessing hierarchical porous characteristics consisting of micrometer-sized cavities superimposed upon a network of nanometer-sized pillars or wires, have been fabricated by a plasma-etching process. These surfaces have superoleophobic properties, after being coated with fluorinated organic trichlorosilanes, on intrinsically oleophilic surfaces. By comparison with flat silicon surfaces, which are oleophilic, it has been demonstrated that a combination of low surface energy and the structured features of the plasma-etched surface is essential to prevent oil from penetrating the surface cavities and thus induce the observed macroscopic superoleophobic phenomena with very low contact-angle hysteresis and low roll-off angles. The structured silicon surfaces were coated with cellulose nanocrystals using the polyelectrolyte multilayer technique. The cellulose surfaces prepared in this way were then coated with a monolayer of fluorinated trichlorosilanes. These porous cellulose films displayed highly nonwetting properties against a number of liquids with low surface tension, including alkanes such as hexadecane and decane. The wettability and chemical composition of the cellulose/silicon surfaces were characterized with contact-angle goniometry and X-ray photoelectron spectroscopy, respectively. The nano/microtexture features of the cellulose/silicon surfaces were also studied with field-emission scanning electron microscopy. The highly oleophobic structured cellulose surfaces are very interesting model surfaces for the development of biomimetic self-cleaning surfaces in a vast array of products, including green constructions, packaging materials, protection against environmental fouling, sports, and outdoor clothing, and microfluidic systems.

Ort, förlag, år, upplaga, sidor
2009. Vol. 1, nr 11, s. 2443-2452
Nyckelord [en]
superoleophobic; cellulose; surface roughness; low surface energy; nanocrystals; polyelectrolyte multilayer; XPS; SEM; oil repellent; coating
Nationell ämneskategori
Pappers-, massa- och fiberteknik
Identifikatorer
URN: urn:nbn:se:kth:diva-11499DOI: 10.1021/am900394yISI: 000272039700006Scopus ID: 2-s2.0-77954574786OAI: oai:DiVA.org:kth-11499DiVA, id: diva2:277315
Anmärkning

QC 20100623

Tillgänglig från: 2009-11-17 Skapad: 2009-11-17 Senast uppdaterad: 2015-06-08Bibliografiskt granskad
Ingår i avhandling
1. Novel oil resistant cellulosic materials
Öppna denna publikation i ny flik eller fönster >>Novel oil resistant cellulosic materials
2009 (Engelska)Doktorsavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

The aim of this study has been to prepare and characterise oil resistant cellulosic materials, ranging from model surfaces to papers and aerogels. The cellulosic materials were made oil resistant by chemical and topographic modifications, based on surface energy, surface roughness and barrier approaches. Detailed wetting studies of the prepared cellulosic materials were made using contact angle measurements and standardised penetration tests with different alkanes and oil mixtures.

A significant part of the activities were devoted to the development of model cellulosic surfaces with different degrees of crystalline ordering for the wetting studies. Crystalline cellulose I, II and amorphous cellulose surfaces were prepared by spin-coating of cellulose nanocrystal or microfibrillated cellulose (MFC) dispersions, with Langmuir-Schaefer (LS) films or by a layer-by-layer (LbL) deposition technique. The formation of multilayers consisting of polyethyleneimine (PEI)/anionic MFC or cationic MFC/anionic MFC was further studied and optimized in terms of total layer thickness and adsorbed amount by combining Dual Polarization Interferometry (DPI) or Stagnation Point Adsorption Reflectrometry (SPAR) with a Quartz Crystal Microbalance with Dissipation (QCM-D).

The smooth cellulosic surfaces prepared had different molecular and mesostructure properties and different surface energies as shown by X-ray diffraction, Atomic Force Microscopy (AFM) imaging, ellipsometry measurements and contact angle measurements.

The cellulose model surfaces were found to be ideal for detailed wetting studies, and after the surface has been coated or covalently modified with various amounts of fluorosurfactants, the fluorinated cellulose films were used to follow the spreading mechanisms of different oil mixtures. The viscosity and surface tension of the oil mixtures, as well as the dispersive surface energy of the cellulose surfaces, were found to be essential parameters governing the spreading kinetics. A strong correlation was found between the surface concentration of fluorine, the dispersive surface energy and the measured contact angle of the oil mixtures.

Silicon surfaces possessing structural porous characteristics were fabricated by a plasma etching process. The structured silicon surfaces were coated with sulfate-stabilized cellulose I nanocrystals using the LbL technique. These artificial intrinsically oleophilic cellulose surfaces were made highly oleophobic when coated with a thin layer of fluorinated silanes. By comparison with flat cellulose surfaces, which are oleophilic, it is demonstrated that the surface energy and the surface texture are essential factors preventing oil from spreading on the surface and, thus, inducing the observed macroscopic oleophobic properties.

The use of the MFC for surface coating on base papers demonstrated very promising characteristics as packaging materials. Environmental-Scanning Electron Microscopy (E-SEM) micrographs indicated that the MFC layer reduced the sheet porosity, i.e. the dense structure formed by the nanofibers resulted in superior oil barrier properties. Attempts were made to link the procedure for preparation of the MFC dispersions to the resulting microstructure of the coatings, and film porosity and the film moisture content to the resulting permeability properties.

Finally, MFC aerogels were successfully prepared by freeze-drying. The surface texture of the porous aerogels was carefully controlled by adjusting the concentration of the MFC dispersion used for the freeze-drying. The different scales of roughness of the MFC aerogels were utilised, together with the very low surface energy created by fluorination of the aerogel, to induce highly oleophobic properties.

Ort, förlag, år, upplaga, sidor
Stockholm: KTH, 2009. s. ix, 55
Serie
Trita-CHE-Report, ISSN 1654-1081 ; 2009:57
Nyckelord
oleophobic, MFC, cellulose, oil resistant, contact angle, XPS, SEM
Nationell ämneskategori
Pappers-, massa- och fiberteknik
Identifikatorer
urn:nbn:se:kth:diva-11494 (URN)978-91-7415-476-4 (ISBN)
Disputation
2009-12-04, F3, Lindstedtvägen 26, KTH, Stockholm, 10:00 (Engelska)
Opponent
Handledare
Anmärkning
QC 20100623Tillgänglig från: 2009-11-17 Skapad: 2009-11-17 Senast uppdaterad: 2019-12-20Bibliografiskt granskad

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Förlagets fulltextScopushttp://pubs.acs.org/doi/abs/10.1021/am900394y

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Wågberg, Lars

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