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Crystal growth of iron(III) flouride trihydrate in mixed acid
KTH, Skolan för kemivetenskap (CHE), Kemiteknik, Teknisk strömningslära.ORCID-id: 0000-0002-3239-5188
KTH, Skolan för kemivetenskap (CHE), Kemiteknik, Teknisk strömningslära.ORCID-id: 0000-0003-1790-2310
(engelsk)Manuskript (preprint) (Annet vitenskapelig)
HSV kategori
Identifikatorer
URN: urn:nbn:se:kth:diva-14096OAI: oai:DiVA.org:kth-14096DiVA, id: diva2:329679
Merknad
QC 20100713Tilgjengelig fra: 2010-07-13 Laget: 2010-07-13 Sist oppdatert: 2022-09-13bibliografisk kontrollert
Inngår i avhandling
1. Crystallization of Metal Fluoride Hydrates from Mixed Acid Solutions
Åpne denne publikasjonen i ny fane eller vindu >>Crystallization of Metal Fluoride Hydrates from Mixed Acid Solutions
2009 (engelsk)Doktoravhandling, med artikler (Annet vitenskapelig)
Abstract [en]

In this work crystal growth and nucleation of b-FeF3×3H2O and crystallization of chromium (III), iron (III) and nickel (II) fluoride hydrates from mixed acid (1-3 mol/kg HNO3 and 1-6 mol/kg free HF) have been investigated.

The solubility of b-FeF3×3H2O has been determined in solutions of different hydrofluoric acid (1-7mol/ kg) and nitric acid (0-7mol/ kg) concentrations at 30, 40 and 50°C. The total iron concentration at equilibrium ranges from about 1 to 35 g/kg solution. In the range of investigated conditions the solubility in terms of total iron content increases with increasing temperature and decreases with increasing concentration of hydrofluoric acid and nitric acid. The results are analysed by examining the chemical speciation in the solutions.

The crystal growth kinetics of b-FeF3×3H2O crystals have been studied by performing seeded isothermal desupersaturation experiments in solutions of 1.5-3.0 mol/ kg nitric acid and 1.4- 5.6 mol/ kg free hydrofluoric acid at 30, 40 and 50°C. The results show that the crystal growth is surface integration controlled. When the driving force is based on a proper speciation no clear correlation of the growth rate with hydrofluoric acid or nitric acid concentration is found. The rate is about the same in industrial pickle liquor as in pure acid solutions. The growth rate at a supersaturation ratio (c(FeF3)free/cs(FeF3)free) of 2 was found to be 5.2×10-12m/s at 30°C, 7.9×10-12m/s at 40°C and 20×10-12m/s at 50°C. Thus, the crystal growth rate at 50°C is about four times higher than at 30°C. The temperature dependence of the rate constant corresponds to an activation energy of 55kJ/ mol.

Crystallization from solutions supersaturated with both Cr(III) and Fe(III) has been investigated and it has been observed that Fe(III) and Cr(III) crystallizes in the form of Cr(Fe)F3×3H2O which is isostructural with CrF3×3H2O. Iron(III) and nickel(II) crystallizes into an unidentified fluoride hydrate crystal.

The crystal growth rate of CrF3×3H2O at 50°C is about the same as the growth rate of b-FeF3×3H2O crystals.

sted, utgiver, år, opplag, sider
Stockholm: KTH, 2009. s. xii, 65
Serie
Trita-CHE-Report, ISSN 1654-1081 ; 2009:27
Emneord
crystallization, crystal growth, b-FeF3.3H2O, iron fluoride trihydrate, CrF3.3H2O, pickling, pickle bath, hydrofluoric acid, nitric acid, stainless steel
HSV kategori
Identifikatorer
urn:nbn:se:kth:diva-10619 (URN)978-91-7415-348-4 (ISBN)
Disputas
2009-06-12, D2, Lindstedtsvägen 5, Stockholm, 10:00 (engelsk)
Opponent
Veileder
Merknad
QC 20100713Tilgjengelig fra: 2009-06-04 Laget: 2009-06-04 Sist oppdatert: 2022-09-13bibliografisk kontrollert

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