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Crystal structures of the trifluoromethyl sulfonates M(SO3CF3)(2) (M = Mg, Ca, Ba, Zn, Cu) from synchrotron X-ray powder diffraction data
KTH, Skolan för kemivetenskap (CHE), Kemiteknik, Tillämpad elektrokemi.
2006 (Engelska)Ingår i: Acta Crystallographica Section B: Structural Science, ISSN 0108-7681, E-ISSN 1600-5740, Vol. 62, s. 467-473Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

The crystal structures of divalent metal salts of trifluoromethyl sulfonic acid ('trifluoromethyl sulfonates') M( SO3CF3)(2) (M = Mg, Ca, Ba, Zn, Cu) were determined from high-resolution X-ray powder diffraction data. Magnesium, calcium and zinc trifluoromethyl sulfonate crystallize in the rhombohedral space group R (3) over bar . Barium trifluoromethyl sulfonate crystallizes in the monoclinic space group I2= a(C2/c) and copper trifluoromethyl sulfonate crystallizes in the triclinic group P (1) over bar. Within the crystal structures the trifluoromethyl sulfonate anions are arranged in double layers with the apolar CF3 groups pointing towards each other. The cations are located next to the SO3 groups. The symmetry relations between the different crystal structures have been analysed.

Ort, förlag, år, upplaga, sidor
2006. Vol. 62, s. 467-473
Nyckelord [en]
gel polymer electrolyte, abinitio structure determination, cross-linked polymers, paddle-wheel, zinc trifluoromethanesulfonate, poly(ethylene oxide), anion reorientation, magnesium triflate, ionic-conductivity, percolation model
Identifikatorer
URN: urn:nbn:se:kth:diva-15671ISI: 000237552600011OAI: oai:DiVA.org:kth-15671DiVA, id: diva2:333713
Anmärkning
QC 20100525Tillgänglig från: 2010-08-05 Skapad: 2010-08-05 Senast uppdaterad: 2017-12-12Bibliografiskt granskad

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Hildebrandt, Lars
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