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Magnetism-driven anomalous surface alloying between Cu and Cr
KTH, Skolan för industriell teknik och management (ITM), Materialvetenskap, Tillämpad materialfysik.
Vise andre og tillknytning
2009 (engelsk)Inngår i: Applied Physics Letters, ISSN 0003-6951, E-ISSN 1077-3118, Vol. 94, nr 17Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Cu-Cr contact materials are widely used as medium- and high-voltage vacuum interrupters. The microstructure of these materials is critical in their performance: the finer structure they have, the better are their physical properties. A solid solution of Cu and Cr could significantly increase the performance of such contact materials. However, Cu and Cr are practically immiscible in the bulk phase. Based on first principles density functional theory we show here that the solubility of Cr in Cu is dramatically increased on Cu surfaces already at room temperature and Cu-Cr alloys are formed on both the Cu(111) and Cu(100) surfaces. We demonstrate that the origin of this phenomenon is the unique magnetic properties of Cr atoms near surfaces.

sted, utgiver, år, opplag, sider
2009. Vol. 94, nr 17
Emneord [en]
chromium alloys, copper, copper alloys, crystal microstructure, density, functional theory, solid solutions, solubility, surface alloying, surface magnetism, potential model, metals, vacuum, approximation, contacts, growth, energy, copper, iron
Identifikatorer
URN: urn:nbn:se:kth:diva-18379DOI: 10.1063/1.3116649ISI: 000265738700046Scopus ID: 2-s2.0-65449181160OAI: oai:DiVA.org:kth-18379DiVA, id: diva2:336425
Merknad
QC 20100525Tilgjengelig fra: 2010-08-05 Laget: 2010-08-05 Sist oppdatert: 2017-12-12bibliografisk kontrollert

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