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Synthesis of Benzotriazine and Aryltriazene Derivatives Starting from 2-Azidobenzonitrile Derivatives
KTH, Skolan för kemivetenskap (CHE), Kemi, Oorganisk kemi.
2010 (engelsk)Inngår i: European Journal of Organic Chemistry, ISSN 1434-193X, E-ISSN 1099-0690, nr 34, s. 6588-6599Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

3-Substituted 3,4-dihydro-4-imino-1,2,3-benzotriazine derivatives 7 were formed from 2-azidobenzonitriles 4 as starting materials on treatment with Grignard or lithium organic reagents. In some cases these procedures gave aryltriazenes 10 and 11 as products. All compounds were identified by NMR spectroscopy and the structures of three products, namely 7a, 10a and 11i, were corroborated by X-ray crystallography.

sted, utgiver, år, opplag, sider
2010. nr 34, s. 6588-6599
Emneord [en]
Nitrogen heterocycles, Grignard reaction, Substituent effects, Azides, Nitriles
HSV kategori
Identifikatorer
URN: urn:nbn:se:kth:diva-28598DOI: 10.1002/ejoc.201000328ISI: 000285262700013Scopus ID: 2-s2.0-78649533140OAI: oai:DiVA.org:kth-28598DiVA, id: diva2:388085
Merknad
QC 20110117Tilgjengelig fra: 2011-01-17 Laget: 2011-01-17 Sist oppdatert: 2017-12-11bibliografisk kontrollert

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