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A joint use of melting and freezing data in NMR cryoporometry
KTH, Skolan för kemivetenskap (CHE), Kemi, Fysikalisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Centrum för Industriell NMR-teknik.
KTH, Skolan för kemivetenskap (CHE), Kemi, Fysikalisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Centrum för Industriell NMR-teknik.ORCID-id: 0000-0002-0231-3970
2010 (Engelska)Ingår i: Microporous and Mesoporous Materials, ISSN 1387-1811, E-ISSN 1873-3093, Vol. 136, nr 1-3, s. 83-91Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Freezing and melting behaviour of water, benzene, cyclooctane and cyclohexane confined in different-sized controlled pore glasses (CPG's) has been studied by NMR cryoporometry technique. It was found that the freezing (Delta Tf) and melting (Delta Tm) temperature shifts correlate linearly, giving a constant ratio AT, Delta Tm/Delta Tf over different fluids. This suggests that the ratio is a measure of pore morphology rather than fluid's properties. The suggestion is supported by the theoretical treatment that predicts for Delta Tf to be controlled by the surface-to-volume ratio (S/V) and Delta Tm, by the pore curvature (dS/dV). Therefore, the ratio Delta Tm/Delta Tf provides one with the information on the pore shape, unavailable from Delta Tf or AT, measurements alone. For CPG samples under study, this ratio decreases from 0.67 in 7.5 nm pores, which is expected for spherical geometry, to 0.57 in 27.3 and 72.9 nm pores, which is closer to what is expected for cylindrical, or tubular, pores. The pore size distribution functions obtained from the freezing and melting data were found to be similar in shape and width, which indicates that melting and freezing processes occur in CPG on the same length scale of the pore structure.

Ort, förlag, år, upplaga, sidor
2010. Vol. 136, nr 1-3, s. 83-91
Nyckelord [en]
Controlled pore glass, NMR cryoporometry, Freezing-melting hysteresis, Morphology
Nationell ämneskategori
Fysikalisk kemi
Identifikatorer
URN: urn:nbn:se:kth:diva-26253DOI: 10.1016/j.micromeso.2010.08.001ISI: 000283204900011Scopus ID: 2-s2.0-77956872858OAI: oai:DiVA.org:kth-26253DiVA, id: diva2:393239
Forskningsfinansiär
VetenskapsrådetKnut och Alice Wallenbergs Stiftelse
Anmärkning
QC 20110129Tillgänglig från: 2011-01-29 Skapad: 2010-11-21 Senast uppdaterad: 2017-12-11Bibliografiskt granskad

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Furo, Istvan

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Petrov, Oleg V.Furo, Istvan
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Fysikalisk kemiCentrum för Industriell NMR-teknik
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Microporous and Mesoporous Materials
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