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Dynamic Kinetic Asymmetric Domino Oxa-Michael/Carbocyclization by Combination of Transition-Metal and Amine Catalysis: Catalytic Enantioselective Synthesis of Dihydrofurans
Vise andre og tillknytning
2010 (engelsk)Inngår i: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 16, nr 47, s. 13930-13934Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

A one-pot highly chemo- and enantioselective catalytic domino oxa-Michael/carbocyclization between α,β-unsaturated aldehydes and propargylic alcohols is presented. This dynamic kinetic transformation requires a combination of transition-metal and amine catalysis to afford functionalized dihydrofurans in good to high yields and up to 99.5:0.5 e.r.

sted, utgiver, år, opplag, sider
2010. Vol. 16, nr 47, s. 13930-13934
Emneord [en]
asymmetric catalysis, co-catalysis, domino reactions, furans, palladium
Identifikatorer
URN: urn:nbn:se:kth:diva-30558DOI: 10.1002/chem.201001992ISI: 000286289700006PubMedID: 21082625Scopus ID: 2-s2.0-78650292001OAI: oai:DiVA.org:kth-30558DiVA, id: diva2:401133
Forskningsfinansiär
Swedish Research Council
Merknad
QC 20110301Tilgjengelig fra: 2011-03-01 Laget: 2011-02-28 Sist oppdatert: 2020-03-09bibliografisk kontrollert

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