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Multielectron-Transfer Templates via Consecutive Two-Electron Transformations: Iron-Sulfur Complexes Relevant to Biological Enzymes
Vise andre og tillknytning
2012 (engelsk)Inngår i: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 18, nr 44, s. 13968-13973Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

[FeFe] hydrogenase mimics: Two polynuclear iron-sulfur complexes (1 and 2; see figure) were prepared and structurally characterized. They are potentially effective and stable multielectron-transfer relays for mediating four- and six-electron transformations via a cascade of reversible two-electron redox steps with relatively narrow potential spans.

sted, utgiver, år, opplag, sider
2012. Vol. 18, nr 44, s. 13968-13973
Emneord [en]
electrochemistry, electron transfer, hydrogenase, iron complexes
HSV kategori
Identifikatorer
URN: urn:nbn:se:kth:diva-106141DOI: 10.1002/chem.201201326ISI: 000310473900009Scopus ID: 2-s2.0-84867808441OAI: oai:DiVA.org:kth-106141DiVA, id: diva2:573367
Forskningsfinansiär
Swedish Research CouncilKnut and Alice Wallenberg Foundation
Merknad

QC 20121130

Tilgjengelig fra: 2012-11-30 Laget: 2012-11-29 Sist oppdatert: 2017-12-07bibliografisk kontrollert

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