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Dye-Sensitized Solar Cells Based on a Donor-Acceptor System with a Pyridine Cation as an Electron-Withdrawing Anchoring Group
Vise andre og tillknytning
2012 (engelsk)Inngår i: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 18, nr 50, s. 16196-16202Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

New hemicyanine dyes (CM101, CM102, CM103, and CM104) in which tetrahydroquinoline derivatives are used as electron donors and N-(carboxymethyl)-pyridinium is used as an electron acceptor and anchoring group were designed and synthesized for dye-sensitized solar cells (DSSCs). Compared with corresponding dyes that have cyanoacetic acid as the acceptor, N-(carboxymethyl)-pyridinium has a stronger electron-withdrawing ability, which causes the absorption maximum of dyes to be redshifted. The photovoltaic performance of the DSSCs based on dyes CM101CM104 markedly depends on the molecular structures of the dyes in terms of the n-hexyl chains and methoxyl. The device sensitized by dye CM104 achieved the best conversion efficiency of 7.0?% (Jsc=13.4 mA?cm-2, Voc=704 mV, FF=74.8?%) under AM 1.5 irradiation (100 mW?cm-2). In contrast, the device sensitized by reference dye CMR104 with the same donor but the cyanoacetic acid as the acceptor gave an efficiency of 3.4?% (Jsc=6.2 mA?cm-2, Voc=730 mV, FF=74.8?%). Under the same conditions, the cell fabricated with N719 sensitized porous TiO2 exhibited an efficiency of 7.9?% (Jsc=15.4 mA?cm-2, Voc=723 mV, FF=72.3?%). The dyes CM101CM104 show a broader spectral response compared with the reference dyes CMR101CMR104 and have high IPCE exceeding 90?% from 450 to 580 nm. Considering the reflection of sunlight, the photoelectric conversion efficiency could be almost 100?% during this region.

sted, utgiver, år, opplag, sider
2012. Vol. 18, nr 50, s. 16196-16202
Emneord [en]
cyanoacetic acid, donor-acceptor systems, dyes/pigments, pyridine cation, sensitizers
HSV kategori
Identifikatorer
URN: urn:nbn:se:kth:diva-110065DOI: 10.1002/chem.201200826ISI: 000312163500036Scopus ID: 2-s2.0-84870583875OAI: oai:DiVA.org:kth-110065DiVA, id: diva2:585557
Forskningsfinansiär
Knut and Alice Wallenberg Foundation
Merknad

QC 20130110

Tilgjengelig fra: 2013-01-10 Laget: 2013-01-10 Sist oppdatert: 2017-12-06bibliografisk kontrollert

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