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The first peripherally masked thiol dendrimers: a facile and highly efficient functionalization strategy of polyester dendrimers via one-pot xanthate deprotection/thiol-acrylate Michael addition reactions
KTH, Skolan för kemivetenskap (CHE), Fiber- och polymerteknik, Ytbehandlingsteknik.
KTH, Skolan för kemivetenskap (CHE), Fiber- och polymerteknik, Ytbehandlingsteknik.ORCID-id: 0000-0002-9200-8004
2014 (engelsk)Inngår i: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 50, nr 50, s. 6574-6577Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Introducing multiple reactive functional groups at the periphery of dendrimer materials presents considerable challenges if the functionality is able to self-react. An efficient and facile approach to introducing masked thiols at the surface of polyester dendrimers is presented. One-pot, deprotection/thiol-acrylate Michael addition from the xanthate-functional dendritic substrates (generation zero to two) has been achieved for the first time, with high efficiency demonstrated using three acrylates of varying chemistry and avoiding disulfide formation.

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2014. Vol. 50, nr 50, s. 6574-6577
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URN: urn:nbn:se:kth:diva-147441DOI: 10.1039/c3cc49704fISI: 000336837900003Scopus ID: 2-s2.0-84901593993OAI: oai:DiVA.org:kth-147441DiVA, id: diva2:730281
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QC 20140627

Tilgjengelig fra: 2014-06-27 Laget: 2014-06-27 Sist oppdatert: 2017-12-05bibliografisk kontrollert

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