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Corrosion of copper in distilled water without O2 and the detection of produced hydrogen
KTH, Skolan för kemivetenskap (CHE), Kemi, Yt- och korrosionsvetenskap.
Vise andre og tillknytning
2015 (engelsk)Inngår i: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 95, s. 162-167Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

This paper reports on hydrogen pressures measured during ~19,000. h immersion of copper in oxygen-free liquid distilled water. Copper corrosion products have been examined ex-situ by SEM and characterized by XPS and SIMS. XPS strongly indicates a corrosion product containing both oxygen and hydrogen. SIMS shows that oxygen is mainly present in the outer 0.3. μm surface region and that hydrogen penetrates to depths well below the corrosion product. Thermal desorption spectroscopy shows that the reaction product formed near room-temperature is less stable than that formed in air at 350. °C.

sted, utgiver, år, opplag, sider
2015. Vol. 95, s. 162-167
Emneord [en]
A. Copper, B. AES, B. SIMS, B. XPS, C. Hydrogen absorption, C. Oxidation
HSV kategori
Identifikatorer
URN: urn:nbn:se:kth:diva-166896DOI: 10.1016/j.corsci.2015.03.009ISI: 000354001400017Scopus ID: 2-s2.0-84927570949OAI: oai:DiVA.org:kth-166896DiVA, id: diva2:818026
Forskningsfinansiär
Swedish Radiation Safety Authority
Merknad

QC 20150608

Tilgjengelig fra: 2015-06-08 Laget: 2015-05-21 Sist oppdatert: 2017-12-04bibliografisk kontrollert

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