Endre søk
RefereraExporteraLink to record
Permanent link

Direct link
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf
A trinuclear ruthenium complex as a highly efficient molecular catalyst for water oxidation
Dalian University of Technology, China.
Dalian University of Technology, China.
Dalian University of Technology, China.
Dalian University of Technology, China.
Vise andre og tillknytning
2016 (engelsk)Inngår i: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 45, nr 9, s. 3814-3819Artikkel i tidsskrift (Fagfellevurdert) Published
Resurstyp
Text
Abstract [en]

A trinuclear ruthenium complex, 3, was designed and synthesized with the ligand 2,2'-bipyridine-6,6'-dicarboxylic acid (bda) and we found that this complex could function as a highly efficient molecular catalyst for water oxidation in homogeneous systems. This trinuclear molecular water oxidation catalyst, 3, displayed much higher efficiencies in terms of turnover numbers and initial oxygen evolution rate than its counterparts, a binuclear catalyst, 2, and a mononuclear catalyst, 1, in both chemically driven and photochemically driven water oxidation based on either the whole catalytic molecules or just the active Ru centers. The reasons for the superior performance of catalyst 3 were discussed and we believe that multiple Ru centers in a single molecule are indeed beneficial for increasing the probability of the formation of O-O bonds through an intramolecular radical coupling pathway.

sted, utgiver, år, opplag, sider
Royal Society of Chemistry, 2016. Vol. 45, nr 9, s. 3814-3819
HSV kategori
Identifikatorer
URN: urn:nbn:se:kth:diva-185088DOI: 10.1039/c5dt04233jISI: 000371140900021PubMedID: 26820507Scopus ID: 2-s2.0-84959222662OAI: oai:DiVA.org:kth-185088DiVA, id: diva2:919680
Merknad

QC 20160414

Tilgjengelig fra: 2016-04-14 Laget: 2016-04-11 Sist oppdatert: 2017-11-30bibliografisk kontrollert

Open Access i DiVA

Fulltekst mangler i DiVA

Andre lenker

Forlagets fulltekstPubMedScopus

Personposter BETA

Sun, Licheng

Søk i DiVA

Av forfatter/redaktør
Sun, Licheng
Av organisasjonen
I samme tidsskrift
Dalton Transactions

Søk utenfor DiVA

GoogleGoogle Scholar

doi
pubmed
urn-nbn

Altmetric

doi
pubmed
urn-nbn
Totalt: 13 treff
RefereraExporteraLink to record
Permanent link

Direct link
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf