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Electrocatalytic water oxidation by a macrocyclic Cu(II) complex in neutral phosphate buffer
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2016 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 52, no 68, 10377-10380 p.Article in journal (Refereed) Published
Abstract [en]

A single-site copper complex, [Cu(TMC)(H2O)](NO3)(2) (1, TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane), was found to be the most active copper-based catalyst towards electrocatalytic water oxidation in neutral aqueous solution. Complex 1 leads to a cathodic shift of approximately 200 mV in potential to reach a current density of 1 mA cm(-2) in comparison with that of the previously reported dinuclear copper complex under the same conditions. Upon immobilization of complex 1 on carbon cloth, it shows greatly improved activity than other copper-based WOCs including CuOx and Cu2+.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2016. Vol. 52, no 68, 10377-10380 p.
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Chemical Sciences
URN: urn:nbn:se:kth:diva-193261DOI: 10.1039/c6cc04884fISI: 000382119600012PubMedID: 27480218ScopusID: 2-s2.0-84983340601OAI: diva2:1033627

QC 20161007

Available from: 2016-10-07 Created: 2016-09-30 Last updated: 2016-10-07Bibliographically approved

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