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Kinetics and Thermodynamics of Constitutional Dynamic Coordination Systems Based on Fe-II, Co-II, Ni-II, Cu-II, and Zn-II
KTH, School of Chemical Science and Engineering (CHE), Chemistry.ORCID iD: 0000-0003-2865-2513
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.
2016 (English)In: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-1948, no 24, 3950-3956 p.Article in journal (Refereed) Published
Abstract [en]

The self-adaptation of constitutional dynamic systems based on selective coordination between 5,5-dimethyl-2,2-bipyridine and deuterium-labeled 4,4-dimethyl-2,2-bipyridine to Fe-II, Co-II, Ni-II, Cu-II, or Zn-II has been evaluated by ESI-MS in methanol. The equilibration rates of the systems proved dependent on the metal species, following the order Zn-II > Cu-II > Co-II > Ni-II > Fe-II, where Zn-II resulted in rapid rearrangement of the original homoleptic complexes. The heteroleptic complexes were favored in the systems with Co-II, Cu-II and Zn-II, whereas the homoleptic complexes were more pronounced with Fe-II and Ni-II.

Place, publisher, year, edition, pages
Wiley-VCH Verlagsgesellschaft, 2016. no 24, 3950-3956 p.
Keyword [en]
Constitutional dynamic systems, Self-organisation, Kinetics, Thermodynamics
National Category
Chemical Sciences
URN: urn:nbn:se:kth:diva-194018DOI: 10.1002/ejic.201600331ISI: 000383609000012ScopusID: 2-s2.0-84983567722OAI: diva2:1038600
EU, FP7, Seventh Framework Programme, 264645Swedish Research Council

QC 20161019

Available from: 2016-10-19 Created: 2016-10-14 Last updated: 2016-10-19Bibliographically approved

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Neranon, KitjanitRamström, Olof
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