Tetra- and Octapyrroles Synthesized from Confusion and Fusion Approaches
2016 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 18, no 19, 5046-5049 p.Article in journal (Refereed) Published
By oxidation of an alternately N-confused bilane in CH2Cl2, a C-N fused tetrapyrrin was synthesized that bears a 5.5.5-tricyclic ring generated from an intramolecular C-N linkage. When CH3CN was used as the reaction medium, a multiply C-N-fused octapyrrolic dimer was also obtained that contained two 126.96.36.199.5-pentacyclic moieties and a bipyrrole unit generated from the intramolecular C-N linkage and intermolecular C-C linkage, respectively. This could be coordinated with Ni(acac)(2) to afford a mixed-ligand complex.
Place, publisher, year, edition, pages
American Chemical Society (ACS), 2016. Vol. 18, no 19, 5046-5049 p.
IdentifiersURN: urn:nbn:se:kth:diva-196076DOI: 10.1021/acs.orglett.6b02495ISI: 000385053900074PubMedID: 27676364ScopusID: 2-s2.0-84990818624OAI: oai:DiVA.org:kth-196076DiVA: diva2:1047102
QC 201611162016-11-162016-11-112016-11-16Bibliographically approved