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Highly oriented MOF thin film-based electrocatalytic device for the reduction of CO2 to CO exhibiting high faradaic efficiency
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2016 (English)In: Journal of Materials Chemistry A, ISSN 2050-7488, Vol. 4, no 40, 15320-15326 p.Article in journal (Refereed) Published
Abstract [en]

A monolithic, highly electrochemically efficient Re-based metal-organic framework (MOF) thin film has been deposited onto a conductive FTO electrode by liquid-phase epitaxy. The X-ray diffraction (XRD) analysis reveals the presence of a highly oriented film grown exclusively along the [001] direction. This epitaxially-grown SURMOF exhibits an extremely high faradaic efficiency of 93 +/- 5% when operated as an electrocatalyst for the reduction of CO2 to CO. In addition, the obtained current densities of the high-quality monolithic coatings exceed 2 mA cm(-2), a value at least one order of magnitude larger than that reported for previous electrocatalytically active MOF thin films.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2016. Vol. 4, no 40, 15320-15326 p.
Keyword [en]
Carbon dioxide, Crystalline materials, Efficiency, Electrocatalysis, Electrocatalysts, Java programming language, Organometallics, Rhenium, X ray diffraction analysis, Electrocatalytic, Epitaxially grown, Faradaic efficiencies, High quality, Highly oriented films, Metal organic framework, Monolithic coatings, Reduction of co
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-196652DOI: 10.1039/c6ta04801cISI: 000386310600007Scopus ID: 2-s2.0-84992700463OAI: oai:DiVA.org:kth-196652DiVA: diva2:1047252
Funder
Swedish Energy AgencyKnut and Alice Wallenberg Foundation
Note

QC 20161117

Available from: 2016-11-17 Created: 2016-11-17 Last updated: 2016-11-17Bibliographically approved

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